稠油中全组分检测方案(气质联用仪)

智能文字提取功能测试中

：等高图显示：20160729091930-稠油3.5ul Mass.ewt 东西分析 稠油样品检测报告 1项目信息 项目名称：稠油样品组分的测定 样品名称：稠油 2实验部分 2.1主要设备与试剂 东西分析 GC×GC-TOF MS 3300 型全二维气质联用仪 分析天平、冰箱、25mL具塞玻璃试管、移液枪。 试剂： CS2溶剂 2.2样品处理 准确称取1g稠油样品，放入25mL具塞玻璃试管中，准确加入 5mLCS2并密封试管，置于于旋混合器上涡旋 2min， 混匀后取 0.5ul 上 GCxGC-TOF MS 分析。 2.4分析条件 色谱条件： 第一维色谱柱DB-5(30mx0.25mm×0.25um)石英毛细管柱，第二维色谱柱 DB-17HT(3mx0.25mmx0.25um)石英毛细管柱； 恒流模式，柱流量1mL/min，不分流进样，分流阀打开时间45s，进样量：0.35uL，进样口：300℃，吹扫流量：2mL/min。调制周期 12s。 第一维维温：60℃保持 3min， 然后以 1℃/min 速率升至200℃保持 5min， 再以10℃/min 升至310℃保持 10min。第二维柱温：60℃保持3min， 然后以1℃/min 速率升至200℃保持5min ， 再以 10℃/min 升至310℃保持10min。调制器热喷温度恒定330℃. 质谱条件：EI源，离子源温度：260℃，接口温度：280℃，电离电压：70V，检测电压：-1800，扫描范围：40~650u， 溶剂延迟： 4min。 3实验结果 3.1稠油样品谱图 稠油样品用 CS2 溶解后直接进全二维气质仪，经过条件优化试验得知，样品在90℃到200℃之间基质非常复杂，选择非常慢的升温程序，样品基本得到完全分离，得到的总离子流图见图1和图2. 图1 用CS2溶解的稠油样品二维显示总离子流图 2016072909 w油3.5ulMass.e 图22月用CS2溶解的稠油样品三维显示总离子流图 通过谱库自动检索，得到定性报告，附表1列出了一一分化合物。检测到稠油样品的组分基本都是小分子量烷烃、环烷烃、烯烃，芳香烃非常少。当柱温高于200℃时， 只能检测到正构烷烃，正构烷烃最高分子量只能达到 C28。 4结果讨论 由于稠油样品基质复杂，，一般溶剂很难溶解此样品。本次实验选择了 CS2溶解稠油样品。程序升温过程中在90℃到200℃之间，样品组分非常多，很难分离。采用加长二维柱以及降低升温速度，样品也没有达到完全分离，附表中的定性化合物也只能作为参考，不一定准确。当柱温高于200℃时，检测到的组分只有正构烷烃，最高只能达到 C28。 本实验难点：1、稠油大多是高分子化合物，很难汽化；2、没有找到合适的溶剂溶解；3、没有明确需要分析的目标化合物，所以没有合适的样品前处理；4、样品基质复杂，对仪器污染较为严重。5、由于样品的污染柱头或样品溶剂不合适，造成峰拖尾。 附表1.稠油样品(溶剂CS2)部分定性表(仅作参考) 1D 2D time 化合物名称 Match 分子式 分子量 CAS 7.15 10.69 Sulfur dioxide 93 02S 64 744609 9.93 8.29 Methyl 2-hydroxydecanoate 69 C11H2203 202 712712 12.7 0.56 1-Dodecyn-4-ol 68 C12H220 182 746463 12.7 1.27 1，5-Heptadiene，2-methyl-， (Z)- 59 C8H14 110 410446 11.95 14.33 3-Hexanone， 2，2-dimethyl- 78 C8H160 128 540579 12.2 0.79 trans-8a-Methylperhydroazulen-4(1H)-one 61 C11H180 166 321664 11.95 7.35 Phenol 79 C6H6O 94 108952 11.95 0.13 Hexanenitrile， 5-methyl- 73 C7H13N 111 194243 12.7 1.32 Norbornane， 2-isobutyl- 73 C11H20 152 181271 12.7 2.21 1，5-Hexadiene， 3-methyl- 66 C7H12 96 154133 12.7 3.87 1-Pentanol，3-methyl- 74 C6H14O 102 589355 13.21 0.37 1-Undecyn-4-ol 72 C11H200 168 221278 13.71 1.04 4-Nonene， 2，3，3-trimethyl-，(Z)- 75 C12H24 168 638306 12.96 14.9 Isobutyl nitrite 73 C4H9NO2 103 542563 13.96 1.66 4-Ethyl-2-hexynal 64 C8H120 124 719329 14.72 1.02 5-Undecene， 5-methyl-，(Z)- 71 C12H24 168 570249 14.72 2.02 Bicyclo[4.1.0]heptane， 3，7，7-trimethyl-，[1S-(1.alpha.，3.alpha.，6.alpha.)]- 70 C10H18 138 606997 14.72 3.76 Propane， 2-methyl-2-nitro- 75 C4H9NO2 103 594707 13.71 14.44 Heptane， 2，5，5-trimethyl- 79 C10H22 142 118999 15.23 1.61 4-Octene， 2，6-dimethyl-， [S-(Z)]- 80 C10H20 140 629607 15.98 0.74 4-Nonene， 2，3，3-trimethyl-， (E)- 69 C12H24 168 638306 15.98 2.29 Bicyclo[3.1.1]heptan-3-one， 2，6，6-trimethyl-，(1.alpha.，2.beta.，5.alpha.)- 71 C10H16O 152 153588 16.24 3.17 5-Undecyne 71 C11H20 152 229472 16.49 1.07 Cyclohexanemethanol， 4-(1-methylethyl)-， trans- 68 C10H200 156 136741 16.74 1.61 trans-8a-Methylperhydroazulen-4(1H)-one 66 C11H18O 166 321664 16.74 2.39 1，4-Heptadiene， 3，3，6-trimethyl- 65 C10H18 138 744988 16.74 3.66 Cyclopropane， 1-(1-methylethyl)-2-(2-methyl-1-methylenepropyl)- 66 C11H20 152 562591 17.24 1.07 3-Decene， 2，2-dimethyl-，(E)- 62 C12H24 168 554990 17.24 1.65 2-Decyne 59 C10H18 138 238470 17.24 2.27 Cyclohexane， 1-ethyl-1，3-dimethyl-， cis- 70 C10H20 140 622383 17.24 2.87 trans-4-tert-butylcycloheptanol 70 C11H220 170 622153 17.24 3.3 Cyclohexene， 1-butyl- 78 C10H18 138 328253 17.24 5.45 1，5-Hexadiene， 2-methyl- 76 C7H12 96 404981 17.5 1.6 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 67 C15H28 208 297884 17.75 2.13 Cyclohexanemethanol，4-(1-methylethyl)-， trans- 71 C10H20O 156 136741 17.75 2.81 4-Octene，2，3，6，7-tetramethyl- 75 C12H24 168 638306 17.75 3.61 Bicyclo[4.1.0]heptane， 3，7，7-trimethyl-，[1S-(1.alpha.，3.alpha.，6.alpha.)]- 72 C10H18 138 606997 18 4.04 3-Octyne， 2，2，7-trimethyl- 63 C11H20 152 554021 18.51 1.73 4-Nonene， 2，3，3-trimethyl-，(E)- 71 C12H24 168 638306 东西分析 18.51 2.92 2-Propen-1-one， 1-(2，2-dimethylcyclopropyl)- 61 C8H120 124 778469 18.25 4.6 Cyclopropane，1-(1-methylethyl)- 2-(2-methyl-1-methylenepropyl)- 66 C11H20 152 562591 18 5.84 Oxirane， (2，2-dimethylpropyl)- 68 C7H14O 114 224529 19.01 2.11 3-Decene， 2，2-dimethyl-， (E)- 75 C12H24 168 554990 19.26 2.92 Cyclohexanemethanol，4-(1-methylethyl)-， trans- 69 C10H200 156 136741 19.26 3.81 1，6-Heptadiene，3-methyl- 73 C8H14 110 508710 19.26 4.4 5，10-Pentadecadien-1-ol，(Z，Z)- 65 C15H28O 224 642755 20.02 1.64 1-Undecyn-4-ol 78 C11H200 168 221278 20.02 1.98 1-Dodecyn-4-ol 74 C12H220 182 746463 20.02 3.63 1，1'-Bicyclopropyl， 2，2，2，2'-tetramethyl- 69 C10H18 138 689982 20.02 4.8 Cyclohexane， butylidene- 70 C10H18 138 227203 20.02 5.7 3-Octyne， 7-methyl- 68 C9H16 124 370500 20.78 0.94 3-Hexanone， 2，2-dimethyl- 79 C8H16O 128 540579 20.27 2.6 1-Hexyl-2-nitrocyclohexane 65 C12H23NO2 213 1.18E+ 20.78 3.34 2，9-Dimethyl-5-decyne 57 C12H22 166 195505 20.02 4.89 4-Decyne 69 C10H18 138 238486 21.03 3.08 3-Decene， 2，2-dimethyl-，(E)- 71 C12H24 168 554990 21.28 5.49 5，10-Pentadecadien-1-ol， (Z，Z)- 70 C15H280 224 642755 21.53 1.91 2-Propen-1-one， 1-(2，2-dimethylcyclopropyl)- 53 C8H12O 124 778469 21.78 3.5 Naphthalene， decahydro-2，2-dimethyl- 69 C12H22 166 311248 21.28 5.47 5，10-Pentadecadien-1-ol，(Z，Z)- 64 C15H280 224 642755 21.78 6.06 Bicyclo[2.2.1]heptane， 2-ethyl- 76 C9H16 124 214641 东西分析 21.53 7.31 2-Nonen-1-ol 74 C9H180 142 221047 22.04 2.35 Cyclohexanemethanol，4-(1-methylethyl)-， trans- 60 C10H200 156 136741 22.54 2.86 4-Octene， 2，3，6，7-tetramethyl- 70 C12H24 168 638306 22.54 2.07 Naphthalene，ecahydro-1，6-dimethyl-4-(1-methylethyl)- 62 C15H28 208 297884 22.29 4.05 Thujone 75 C10H16O 152 546805 23.55 1.21 3-Hexanone， 2，2-dimethyl- 76 C8H160 128 540579 23.8 3.44 4-Octene， 2，3，6，7-tetramethyl- 68 C12H24 168 638306 23.55 4.65 2，9-Dimethyl-5-decyne 64 C12H22 166 195505 24.05 4.86 Naphthalene， decahydro-2，2-dimethyl- 70 C12H22 166 311248 23.55 6.92 3-Nonyne 72 C9H16 124 201848 24.56 4.99 Naphthalene， decahydro-2，2-dimethyl- 68 C12H22 166 311248 24.81 7.58 Norbornane， 2-isobutyl- 74 C11H20 152 181271 25.32 2.38 1-Dodecyn-4-ol 72 C12H22O 182 746463 25.32 3.33 Naphthalene， cahydro-1，6-dimethyl-4-(1-methylethyl)一 68 C15H28 208 297884 25.32 3.99 4-Octene， 2，3，6，7-tetramethyl- 77 C12H24 168 638306 25.32 4.97 1，1'-Bicyclopropyl， 2，2，2'，2'-tetramethyl- 67 C10H18 138 689982 25.57 4.93 Bicyclo[4.1.0]heptane，3，7，7-trimethyl-，.alpha.，3.alpha.，6.alpha.)]- 67 C10H18 138 606997 25.57 7.95 Norbornane， 2-isobutyl- 67 C11H20 152 181271 26.07 3.7 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 79 C15H28 208 297884 26.07 5.68 cis，cis- and cis，trans-1，9-dimethylspiro[4.5]decane 75 C12H22 166 0 25.57 7.97 Cyclodecene， 3-bromo- 64 C10H17Br 216 563255 26.07 10.43 1-Adamantanemethanol 66 C11H180 166 770718 28.59 4.32 Naphthalene，d cahydro-1，6-dimethyl-4-(1-methylethyl) 71 C15H28 208 297884 一 29.1 4.95 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 82 C15H28 208 297884 28.59 6.99 Bicyclo[2.2.1]heptane， 2，2，3-trimethyl-，endo- 67 C10H18 138 205364 28.34 8.5 2-Decen-1-ol 72 C10H200 156 221048 29.6 4.28 Cyclohexane， 1，5-diethyl-2，3-dimethyl- 71 C12H24 168 746636 30.36 4.12 1-Tridecyn-4-ol 71 C13H24O 196 746463 29.86 5.18 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 75 C15H28 208 297884 29.86 7.1 7-Tetradecyne 73 C14H26 194 352161 30.11 7.54 Naphthalene， decahydro-2，2-dimethyl- 68 C12H22 166 311248 30.61 5.37 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 75 C15H28 208 297884 30.61 7.88 Cyclohexane， (2-ethyl-1-methylbutylidene)- 65 C13H24 180 748104 30.61 8.93 1，2-Cyclohexanedimethanol 71 C8H1602 144 397129 31.62 2.4 3-Hexanone， 2，4-dimethyl- 80 C8H16O 128 186417 31.62 4.24 1-Tridecyn-4-ol 68 C13H24O 196 746463 31.62 5.82 Cyclopentene， 5-hexyl-3，3-dimethyl- 71 C13H24 180 611426 31.87 6.36 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 82 C15H28 208 297884 31.87 7.98 5，10-Pentadecadienoic acid，(Z，Z)- 63 C15H2602 238 642756 32.38 5.22 1-Octadecyne 69 C18H34 250 629890 32.38 5.77 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 78 C15H28 208 297884 32.38 6.52 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 73 C15H28 208 297884 32.38 8.73 trans-8a-Methylperhydroazulen-4(1H)-one 66 C11H18O 166 321664 32.38 9.7 Decanal 86 C10H200 156 112312 32.88 4.5 Cyclohexane， 1，5-diethyl-2，3-dimethyl- 67 C12H24 168 746636 32.88 5.95 3-Hexadecyne 66 C16H30 222 618866 33.13 6.67 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 76 C15H28 208 297884 32.88 8.47 3-Decyne 73 C10H18 138 238485 33.64 4.59 1-Hexyl-2-nitrocyclohexane 72 C12H23NO2 213 1.18E+ 33.89 5.93 Cyclopentene， 5-hexyl-3，3-dimethyl- 72 C13H24 180 611426 34.14 7.1 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 74 C15H28 208 297884 34.4 3.74 1-Tridecyn-4-ol 69 C13H24O 196 746463 34.65 6.06 3-Tetradecyne 68 C14H26 194 602123 34.9 7.26 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 76 C15H28 208 297884 35.15 10.33 2-Decyne 63 C10H18 138 238470 35.66 6.77 7-Tetradecyne 71 C14H26 194 352161 35.66 6.08 1-Hexyl-2-nitrocyclohexane 74 C12H23NO2 213 1.18E+ 36.67 7.17 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 70 C15H28 208 297884 36.67 7.71 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 75 C15H28 208 297884 36.92 8.43 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 74 C15H28 208 297884 36.41 8.91 6，10-Dimethyl-9-undecen-4-ol 64 C13H26O 198 197800 37.17 9.19 1，1-Dimethyl-4-methylenecyclohexane 72 C9H16 124 600796 37.68 8.34 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 77 C15H28 208 297884 37.68 7.71 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 68 C15H28 208 297884 37.68 6.25 Methyl2-hydroxydecanoate 64 C11H2203 202 712712 38.18 4.86 3-Decene， 2，2-dimethyl-，(E)- 73 C12H24 168 554990 38.43 4.39 Cyclohexane，1，1'-[1，2-bis(1，1-dimethylethyl)-1，2-ethanediyl]bis-，*，R*)-(.+/-.)- 68 C22H42 306 651498 38.68 5.3 1-Hexyl-2-nitrocyclohexane 75 C12H23NO2 213 1.18E+ 38.94 6.88 Cyclohexane， (2-ethyl-1-methylbutylidene)- 55 C13H24 180 748104 38.43 8.1 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 71 C15H28 208 297884 38.68 8.76 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 72 C15H28 208 297884 39.69 6.09 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-，(2-endo，3-exo，4-exo)-(.+-.)- 60 C12H19NO3 225 1.3E+0 40.2 2.5 Butane， 2，2-dimethyl- 71 C6H14 86 75832 40.7 5.12 4-Nonene， 2，3，3-trimethyl-， (Z)- 76 C12H24 168 638306 40.7 5.61 1-Undecene， 9-methyl- 72 C12H24 168 746304 40.7 6.31 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-，2-endo，3-exo，4-exo)-(.+-.)- 62 C12H19NO3 225 1.3E+0 40.7 7.34 Bicyclo[2.2.1]heptane， 2，2，3-trimethyl-， endo- 62 C10H18 138 205364 40.7 8.37 Bicyclo[2.2.1]heptane， 2，2，3-trimethyl-， endo- 66 C10H18 138 205364 40.7 9.68 cis，trans-2，9-Dimethylspiro[5.5]undecane 68 C13H24 180 955307 40.45 10.69 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 74 C15H28 208 297884 41.96 7.07 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-， 2-endo，3-exo，4-exo)-(.+-.)- 62 C12H19NO3 225 1.3E+0 42.22 8.55 1，3-Hexadiene， 3-ethyl-2-methyl-，(Z)- 65 C9H16 124 747529 42.22 8.98 Cyclohexane， (2-ethyl-1-methylbutylidene)- 68 C13H24 180 748104 42.72 6.07 1-Hexyl-2-nitrocyclohexane 81 C12H23NO2 213 1.18E+ 41.96 5.32 1-Dodecyn-4-ol 67 C12H22O 182 746463 43.73 7.73 1H-Indene， 2-butyl-5-hexyloctahydro- 60 C19H36 264 550443 42.97 9.76 5，10-Pentadecadien-1-ol，(Z，Z)- 68 C15H28O 224 642755 43.22 11.03 trans-8a-Methylperhydroazulen-4(1H)-one 73 C11H18O 166 321664 东西分析 43.48 3.46 Dodecane， 1-iodo- 79 C12H25I 296 429219 44.49 4.99 Cyclohexane， 1，5-diethyl-2，3-dimethyl- 74 C12H24 168 746636 44.23 6.51 1-Hexyl-2-nitrocyclohexane 72 C12H23NO2 213 1.18E+ 44.49 7.53 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-/ 2-endo，3-exo，4-exo)-(.+-.)- 65 C12H19NO3 225 1.3E+0 44.23 11.2 1-Dodecyne 74 C12H22 166 765037 45.75 7.7 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro- 2-endo，3-exo，4-exo)-(.+-.)- 63 C12H19NO3 225 1.3E+0 46.25 8.78 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 68 C15H28 208 297884 45.75 9.99 8-Hexadecyne 61 C16H30 222 197818 45.75 10.75 (2，4，6-Trimethylcyclohexyl) methanol 67 C10H200 156 137025 47.26 5.77 Cyclohexane， 1，5-diethyl-2，3-dimethyl- 74 C12H24 168 746636 47.26 7.83 Bicyclo[2.2.1]heptane， 2，2，3-trimethyl-，endo- 66 C10H18 138 205364 47.76 8.3 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 76 C15H28 208 297884 47.76 9.58 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-/ 2-endo，3-exo，4-exo)-(.+-.)- 64 C12H19NO3 225 1.3E+0 48.02 10.68 trans-(2-Ethylcyclopentyl)methanol 61 C8H16O 128 362580 48.02 4.33 Dodecane， 1-iodo- 74 C12H25I 296 429219 48.77 4.3 Decane，6-ethyl-2-methyl- 71 C13H28 184 621082 48.77 5.28 1-Tridecyn-4-ol 67 C13H24O 196 746463 47.76 8.38 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 72 C15H28 208 297884 48.02 10.65 Thujone 64 C10H16O 152 546805 50.29 6.05 1-Tridecyn-4-ol 70 C13H24O 196 746463 50.29 8.85 1H-Indene， octahydro-2，2，4，4，7，7-hexamethyl-，trans- 57 C15H28 208 548328 51.8 7.07 1-Hexyl-2-nitrocyclohexane 71 C12H23NO2 213 1.18E+ 51.55 10.01 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 72 C15H28 208 297884 51.04 10.67 Cyclohexan-1-ethanol， 1-hydroxymethyl- 67 C9H1802 158 318728 51.3 11.84 3-Undecyne 66 C11H20 152 602123 51.8 12.5 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-/ (2-endo，3-exo，4-exo)-(.+-.)- 64 C12H19NO3 225 1.3E+0 52.3 11.52 Bicyclo[2.2.1]heptane， 2，2，3-trimethyl-，endo- 68 C10H18 138 205364 52.3 3.57 Nonane， 1-iodo- 73 C9H19I 254 428242 53.06 6.88 1-Hexyl-2-nitrocyclohexane 76 C12H23NO2 213 1.18E+ 52.56 8.51 photocitral B 62 C10H16O 152 604045 52.81 9.98 Cyclohexanemethanol， 4-(1-methylethyl)-， trans- 63 C10H200 156 136741 53.82 8.3 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 68 C15H28 208 297884 53.57 9.99 Cyclohexane， 1-methyl-4-(2-hydroxyethyl)- 64 C9H180 142 491687 54.57 8.3 1H-Indene， octahydro-2，2，4，4，7，7-hexamethyl-，trans- 61 C15H28 208 548328 54.83 9.77 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 64 C15H28 208 297884 55.33 9.27 1H-Indene， octahydro-2，2，4，4，7，7-hexamethyl-，trans- 64 C15H28 208 548328 55.33 8.47 1H-Indene， octahydro-2，2，4，4，7，7-hexamethyl-，trans- 60 C15H28 208 548328 56.09 8.82 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 67 C15H28 208 297884 55.33 4.36 Dodecane， 1-iodo- 82 C12H25I 296 429219 56.84 5.62 Cyclohexane， 1，2，4，5-tetraethyl-，(1.alpha.，2.alpha.，4.alpha.，5.alpha.)- 67 C14H28 196 611422 56.84 6.13 1-Tridecyn-4-ol 72 C13H24O 196 746463 57.35 10.38 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-，2-endo，3-exo，4-exo)-(.+-.)- 65 C12H19NO3 225 1.3E+0 55.84 13.65 Pentane， 1-chloro-5-(methylenecyclopropyl)- 56 C9H15CI 158 0 56.34 12.31 1-Undecyne 65 C11H20 152 224398 58.36 10.55 Naphthalene，decahydro-1，6-dimethyl-4-(1-methylethyl)- 68 C15H28 208 297884 东西分析 58.61 11.38 Cyclohexanemethanol，4-(1-methylethyl)-，trans- 65 C10H200 156 136741 59.37 6.84 1-Hexyl-2-nitrocyclohexane 74 C12H23NO2 213 1.18E+ 59.62 12.48 1，4-Heptadiene， 3，3，6-trimethyl- 61 C10H18 138 744988 61.13 6.56 Cyclohexane， 1，2，4，5-tetraethyl-，(1.alpha.，2.alpha.，4.alpha.，5.alpha.)- 72 C14H28 196 611422 60.38 13.11 photocitral A 65 C10H160 152 552532 60.88 13.41 (2，4，6-Trimethylcyclohexyl) methanol 66 C10H200 156 137025 61.89 9.81 1-Hexyl-2-nitrocyclohexane 67 C12H23NO2 213 1.18E+ 61.89 13.67 photocitral A 72 C10H16O 152 552532 63.4 7.21 1，7-Dimethyl-4-(1-methylethyl)cyclodecane 72 C15H30 210 645103 63.15 10.2 Bicyclo[3.3.1]nonan-9-one，1，2，4-trimethyl-3-nitro-， 2-endo，3-exo，4-exo)-(.+-.)- 64 C12H19NO3 225 1.3E+0 66.68 5.24 Dodecane， 1-iodo- 76 C12H25I 296 429219 67.44 6.73 Cyclohexane， 1，2，4，5-tetraethyl-， (1.alpha.，2.alpha.，4.alpha.，5.alpha.)- 73 C14H28 196 611422 66.68 6.34 4-Octene， 2，3，6，7-tetramethyl- 65 C12H24 168 638306 66.68 8.34 1-Hexyl-2-nitrocyclohexane 77 C12H23NO2 213 1.18E+ 66.68 9.12 3-Methyl-2-(2-oxopropyl)furan 58 C8H1002 138 877736 65.92 13.39 2，9-Dimethyl-5-decyne 59 C12H22 166 195505 68.2 6.96 1-Tridecyn-4-ol 71 C13H24O 196 746463 69.2 6.87 Methyl 2-hydroxydodecanoate 67 C13H2603 230 510678 69.96 7.53 4-Octene， 2，3，6，7-tetramethyl- 72 C12H24 168 638306 69.71 10.31 Cyclohexanol，4-ethyl-4-methyl-3-(1-methylethyl)-， (1.alpha.，3.beta.，4.alpha.)- 60 C12H240 184 558695 69.71 11.86 Naphthalene， decahydro-1，6-dimethyl-4-(1-methylethyl)- 64 C15H28 208 297884 69.96 13.96 photocitral A 75 C10H16O 152 552532 72.48 7.49 1-Hexyl-2-nitrocyclohexane 70 C12H23NO2 213 1.18E+ 71.98 14.73 2，5-Octadiene， 3，4，5，6-tetramethyl- 67 C12H22 166 2.48E+ 75.26 9.12 1-Hexyl-2-nitrocyclohexane 77 C12H23NO2 213 1.18E+ 76.01 10.65 3-Methyl-2-(2-oxopropyl)furan 67 C8H1002 138 877736 74.75 14.91 Diphenyl sulfide 70 C12H10S 186 139662 77.78 5.98 Nonane， 1-iodo- 77 C9H19I 254 428242 71.47 1.07 Phthalic acid， isobutyl tridec-2-yn-1-yl ester 61 C25H3604 400 0 78.54 7.4 1-Tridecyn-4-ol 68 C13H24O 196 746463 79.29 7.63 Methyl 2-hydroxydodecanoate 73 C13H2603 230 510678 80.81 7.32 1-Hexyl-2-nitrocyclohexane 70 C12H23NO2 213 1.18E+ 83.08 5.48 2，2，4-Trimethyl-3-pentanone 74 C8H16O 128 585736 85.09 7.17 1-Hexyl-2-nitrocyclohexane 64 C12H23NO2 213 1.18E+ 85.09 7.73 1-Hexyl-2-nitrocyclohexane 71 C12H23N02 213 1.18E+ 84.34 10.7 Naphthalene， decahydro-1，6-dimethyl-4-(1-methylethyl)- 65 C15H28 208 297884 83.83 11.85 1-Hexyl-2-nitrocyclohexane 61 C12H23NO2 213 1.18E+ 88.88 5.6 Dodecane， 1-iodo- 69 C12H25I 296 429219 88.37 6.68 Dodecane， 1-iodo- 77 C12H25I 296 429219 88.12 7.69 1-Tridecyn-4-ol 65 C13H24O 196 746463 88.37 8.33 1-Hexyl-2-nitrocyclohexane 70 C12H23NO2 213 1.18E+ 89.38 11.68 1-Hexyl-2-nitrocyclohexane 66 C12H23NO2 213 1.18E+ 89.63 14.94 trans-Chrysanthemal 65 C10H16O 152 201040 94.43 8.45 Cyclohexane， 1，5-diethyl-2，3-dimethyl- 69 C12H24 168 746636 95.18 14.61 photocitral A 69 C10H16O 152 552532 108.5 0.56 Cyclohexan-1-ethanol， 1-hydroxymethyl- 63 C9H1802 158 318728 110.0 0.51 Cyclohexan-1-ethanol， 1-hydroxymethyl- 61 C9H1802 158 318728 108.0 8.38 4-Octene，2，2，3，7-tetramethyl-，[S-(E)]- 69 C12H24 168 638655 115.8 1.35 2-Dodecyne 62 C12H22 166 629492 117.6 1.38 3，5-Octadien-2-one，(E，E)- 58 C8H120 124 300860 -- -- 稠油（thickened oil），是沥青质和胶质含量较高、黏度较大的原油。通常把地面密度大于0.943、地下黏度大于50毫帕•秒的原油叫稠油。其占全球原油储量的70%，我们利用东西分析GCxGC TOF MS3300全二维气相色谱-飞行时间质谱联用仪分析了稠油的成分组成。