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【求助】交流阻抗中拟合用到Q,Q的两个参数值Y0和n各有什么意义?他们的变化能说明什么问题?

电化学综合讨论

  • 交流阻抗中拟合用到常相角元件Q,Q的两个参数值Y0和n各有什么意义?他们的变化能说明什么问题?
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  • amigo365

    第2楼2007/04/03

    看到楼上同志的回答真是令人失望!
    。。。。。。

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  • old fox

    第3楼2007/04/04

    The impedance of a CPE has the form:

    C=(1/Y0)(Jw)^n

    When this equation describes a capacitor, the constant Y0 = C (the capacitance) and the exponent n = 1. For a constant phase element, the exponent n is less than one.

    The "double layer capacitor" on real cells often behaves like a CPE instead of like a capacitor. Several theories have been proposed to account for the non-ideal behavior of the double layer but none has been universally accepted. In most cases, you can safely treat a as an empirical constant and not worry about its physical basis.

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