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  • yftnb

    第11楼2008/03/20

    书上答案:

    Ions formed in the source of the mass spectrometer must reach the detector for them to be of any value. the average distance that an ion travels between collisions - the mean free path - at atmospheric pressure is around 10-8 m, and it is therefore unlikely that it will reach the detector under these conditions. since the mean free path is inversely proportional to the pressure, reducing this to 10-6 torr will increase the mean free path to around 10 m, and thus allow ions to reach the detector of the mass spectrometer.

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  • flyfish1982

    第12楼2008/03/21

    真空系统是保证色质联用仪正常进行的基础,质谱中样品气态分子在具有一定高真空的离子源中,被灯丝发射的电子轰击成气态离子这些离子(各种碎片离子和分子离子)在高真空的条件下通过质量分析器进入电子倍增器放大记录下来为避免产生不必要的离子一分子反应和减少本底的干扰,质谱的整个过程必须在真空腔的高真空条件下工作。

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  • niuchunhui

    第13楼2008/03/21

    二楼很专业,解释很详细。

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  • wbp

    第14楼2008/04/07

    觉得这种话题实在有点无聊,真空是质谱的生命,实在没有什么好讨论的

    yftnb 发表:如题啊,大家讨论一下

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  • ningbin6

    第15楼2008/04/08

    那个安捷伦培训教材里有讲这个

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  • cuixuefenghehe

    第16楼2008/04/08

    液质新手,持学习态度!

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  • tuqw

    第17楼2008/04/12

    问一下,如果是离子井的,离子井里的真空度应该达到多少?如果我要往下做三级四级,如果浓度很大,离子化效率也可以是不是也有可能是我的真空度不太好?

    yftnb 发表:书上答案:

    Ions formed in the source of the mass spectrometer must reach the detector for them to be of any value. the average distance that an ion travels between collisions - the mean free path - at atmospheric pressure is around 10-8 m, and it is therefore unlikely that it will reach the detector under these conditions. since the mean free path is inversely proportional to the pressure, reducing this to 10-6 torr will increase the mean free path to around 10 m, and thus allow ions to reach the detector of the mass spectrometer.

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  • yszhou

    第18楼2008/04/12

    2搂说的好,学习了!

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  • icecoffee

    第19楼2008/04/22

    而且因為重新保持所需真空度需要約2小時. 所以很多公司一般會一直keep 住在high vaccum狀態

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  • coolkid

    第20楼2008/04/24

    刚接触!学习了

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