方案摘要
方案下载应用领域 | |
检测样本 | |
检测项目 | |
参考标准 |
Highly crystalline, size-controlled Zn2SnO4 nanoparticles are synthesized by hydrothermal synthesis using two different mineralizers, viz., inorganic Na2CO3 and organic tert-butyl amine. The shape and surface properties of the two types of nanoparticles are totally different owing to the structure-directing abilities and the radicals in the mineralizers, even though both types of nanoparticles show a defect-free and highly crystalline structure. Na2CO3 induces faceted planar morphologies with negative surface charges, whereas tert-butyl amine induces roughly spherical shapes with positive surface charges; these changes have been analyzed by SEM, TEM, and zeta potential measurements. Electrochemical tests performed on these two types of nanoparticles indicate a capacity that gradually fades up to the 20th cycle due to the inevitable structural irreversibility. However, the specific discharge/charge capacities of both Zn2SnO4 anodes become almost constant after 20 cycles, and at 40th cycle, the specific discharge capacities of both nanoparticles are 521.4 mAh/g for nanoparticles synthesized using tert-butyl amine and 448.0 mAh/g for nanoparticles synthesized using Na2CO3 with Coulombic efficiencies higher than 96%. Such an excellent cycling stability and reversibility against lithium insertion/extraction can be attributed to the improved pulverization/agglomeration resistances of these materials, resulting from the surface residual charges, i.e., the repulsive forces between like-charged nanoparticles.
用OSP解除SECM中高度的影响--在腐蚀中的应用
华洋科仪:用DPS气相色谱仪进行生物柴油分析
华洋科仪:DPS气相色谱仪专用环境气体分析方法
相关产品
法国Bio-Logic 电化学工作站VSP-300(6通道)
法国Bio-Logic 电化学工作站 HCV-3048 Booster
法国Bio-Logic 电化学工作站FlexP 0060/0012
法国Bio-Logic高电流电化学工作站HCP-803
法国Bio-Logic高精度多通道电池测试系统MPG-2XX
法国Bio-Logic 电化学工作站SP-150e(双通道)
法国Bio-logic 电化学工作站SP-50e(单通道)
SIS-5100光波导光谱仪
全自动微孔板检测圆二色光谱仪
法国Bio-Logic 电化学工作站 VSP-3e(8通道)
法国Bio-Logic微区扫描电化学工作站M470
Bio-Logic圆二色光谱仪MOS-500
BioTools振动圆二色光谱仪ChiralIR-2X
BioTools手性拉曼光谱仪ChiralRAMAN-2X
法国Bio-Logic 电化学工作站 VMP-3e(16通道)
关注
拨打电话
留言咨询