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Mechanically-induced combustion reactions were carried out in a transparent quartz vial. The combustion processes were followed by high-speed video recording and optical pyrometers. Depending on the vial dynamics, the powder particles were seen to gather in a periodic collective motion, behaving like a granular gas characterised by subsequent changes in its density. After ignition, a considerable increase of brightness was observed, due to the extremely rapid propagation of the high-temperature reaction to the whole mass of powder. Experimental observations ?nd a very good correlation if compared to the results of numerical calculations simulating the particle system dynamics. Balls and powder dynamics were reproduced according to a well-known visco-elastic force scheme, while chemical conversion of each powder particle was described by a conventional nucleation-and-growth kinetics. The propagation mechanism of the reaction was studied and related to the dynamic features of the whole system.
【CEM】检测葡萄干、苏丹娜和醋栗中的重金属污染
【Hanson】使用垂直扩散池进行透皮贴剂释放测试
【CEM】Fmoc-His(Boc)-OH在基于Fmoc的固相肽合成中的应用
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