null检测 | Microwave-Assisted Stepwise synthesis-上海屹尧仪器科技发展有限公司

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A unique two-dimensional layer-based material [Cu(μ1,1-N3)2(H2O)][CuL2] (1, L =2-methylpyrazine-5-carboxylate) was produced by a stepwise, microwave-assisted synthesis, featuring linear Cu(II)-μ1,1-azido chains mediated by discrete CuL2 motifs. The mutual stabilization of the zero-dimensional and one-dimensional motifs in the unusual crystalline lattice of 1 is achieved by both coordination and supramolecular interactions. As a consequence, this material represents a novel copper(II)-based metamagnet resulting from the nature of the strong intrachain ferromagnetic coupling versus the weak interchain antiferromagnetic coupling.

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上海屹尧仪器科技发展有限公司

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