每周分享：Oxidation of carbon black, propene and toluene on highly reducible Co/SBA-15 catalysts

麦克默瑞提克(上海）仪器有限公司

2014/11/24 10:49

今天给大家分享的是2014年4月份《Comptes Rendus Chimie》上发表的一篇名为：Oxidation of carbon black, propene and toluene on highly reducible Co/SBA-15 catalysts

文章摘要如下：

Different cobalt loadings (3, 6, 12, 24 wt%) were impregnated using the double-solvent technique on SBA-15 calcined at 500 °C presenting a high specific surface area. The impregnated solids were stabilized at 450 °C in the air. The impregnation of cobalt led to the incorporation of cobalt oxide nanoparticles in the mesoporosity of the SBA-15. The cobalt nanoparticles were easily reducible compared to similar solids prepared by different methods. The presence of these nanoparticles enhanced significantly the reactivity of the catalysts in the considered reaction. The addition of more than 12 wt% of cobalt did not enhance the catalytic reactivity due to the deposition of cobalt oxide species on the surface of the support. The cobalt-impregnated solids are efficient in decreasing the oxidation temperature of different probe molecules and are totally selective towards the formation of CO2 and H2O.

该文章中材料表征采用的是美国麦克仪器AutoChem 2920

详情可参考下面链接：

http://www.sciencedirect.com/science/article/pii/S163107481300341X

阅读193次