资料摘要
资料下载Thermally sensitive poly(N-isopropylacrylamide) (PNIPAM) brushes grafted on SiO2-coated quartz crystal surface were prepared with a surface-immobilized initiator. Using quartz crystal microbalance (QCM), we investigated the collapse and swelling of the brushes in water in real time. Both frequency and dissipation of PNIPAM brushes were found to gradually change throughout a temperature range 20-38 °C, indicating that PNIPAM brushes undergo a continuous collapse transition in contrast with PNIPAM chains free in dilute solution exhibiting a sharp coil-to-globule transition. This result is in accordance with the previous theoretical prediction. The nonuniformity and stretching of PNIPAM brushes as well as the cooperativity between collapse and dehydration transitions are thought to be responsible for the continuity. On the other hand, a hysteresis was also observed in the cooling process. This is not only due to the intrachain and interchain interactions formed in the collapsed state but also to the nonuniform structure and stretching of the high-density brushes.
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简介：The TLS-100 is a portable thermal conductivity meter used to measure thermal conductivity and thermal resistivity. Perfect for testing the thermal conductivity of soil, polymers, viscous liquids, and other soft materials; as well as testing the thermal conductivity of concrete, rock, stone, or other hard materials. Tests can be performed with the push of a button. The collected data is automatically analyzed and results are displayed immediately.
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简介：The Transient Hot Wire (THW-L2) Liquid Thermal Conductivity Meter is an advanced measurement system for direct determination of the thermal conductivity of liquids and pastes in accordance with ASTM D7896. The THW-L2 was designed with speed and operational simplicity in mind. With a single measurement of less than 2 seconds in duration, small volumes of liquids and pastes can be accurately and precisely measured for thermal conductivity. The THW-L2 utilizes a non-stationary measurement approach and rapid test times to limit convective effects for samples with a wide range of viscosities.
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