多孔材料对氢气的吸附性能研究

2017/11/16   下载量: 2

方案摘要

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应用领域 石油/化工
检测样本 单质
检测项目 理化分析
参考标准

Hydrogen isotherms for MOF-177, Zn4O(1,3,5-benzenetribenzoate)2, crystals were independently measured by volumetric and gravimetric methods at 77 K to confirm its hydrogen uptake capacity and to establish the importance of calibrating gas adsorption instrumentation prior to evaluating H2 storage capacities. Reproducibility of hydrogen adsorption experiments is important because non-systematic errors in measurements can easily occur leading to erroneous reports of capacities. The surface excess weight percentage of hydrogen uptake in MOF-177 samples is 7.5 wt% at 70 bar, which corresponds to an absolute adsorbed amount of 11 wt%. These values are in agreement with our previous report and with those found independently by Southwest Research Institute. Considering its well-known structure and its significant H2 uptake properties, we believe MOF-177 is an excellent material to serve as a benchmark adsorber.

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