聚氨酯树脂材料中的异氰酸酯

2012/04/23   下载量: 9

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Polyurethane has an excellent flexibility, adhesiveness and high impregnation rate, widely utilized such as automotive films, insulating materials, and paints. The polyurethane resin is a polymer which involves the urethane bond, obtained by the polymerization reaction between polyisocyanate and polyol (also called, polyester or polyether). ・・―NCO + HO―・・ 􀃆 ・・―NHCOO― … (1) ―NCO + H2N―・・ 􀃆 ・・―NHCONH― … (2) ・・H2N―(excessive) + HCl 􀃆 HCl・H2N― … (3) (B-D)×K×F×M S×1000 A1 : Content of isocyanate groups (%) F : Factor of the titrant D : Volume of the titrant consumed (mL) M : Molarity of the titrant (0.5) B : Blank value (mL) S : Weight of the sample added (g) K : Formula weight of isocyanate (42.02)

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