酸性和碱性介质水溶液中粉煤灰和钠沸石的重金属浸出试验中样品的24小时振荡

2023/08/15   下载量: 0

方案摘要

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应用领域 材料
检测样本 薄膜材料
检测项目
参考标准 HJ 557-2010 固体废物 浸出毒性浸出方法 水平振荡法

混合Na-A沸石氧切薄膜复合纳滤膜去除Cr(III)三价铬Hybrid Na-A Zeolite Oxycut Residue Thin Film Composite Nanofiltration Membrane for Cr (Iii) Removal 使用格哈特振荡器100rpm振荡24小时

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混合Na-A沸石氧切薄膜复合纳滤膜去除Cr(III)三价铬Hybrid Na-A Zeolite Oxycut Residue Thin Film Composite Nanofiltration Membrane for Cr (Iii) Removal

2.3.2 Leaching tests  A heavy metal leaching test from fly ash and Na-A zeolite was investigated in aqueous solutions in both acid and alkaline  media, adjusted by hydrochloric acid and sodium hydroxide solutions. Suspensions containing 0.05 g of zeolite and fly  ash, in 10 ml of solution at pH values of 2, 5, 7, 9, and 11, were agitated for 24 h at 100 rpm (Gerhardt Laboshake). The  pH of the leachate was measured using a pH meter (Mettler-Toledo), and samples were filtered and analyzed by ICP-MS (Perkin Elmer ICP-MS, Optima 8300).  使用格哈特振荡器100rpm振荡24小时

2.3.3 Adsorption studies of Cr (III) Batch tests were conducted to determine the metal adsorption by shaking at 100 rpm (Gerhardt Laboshake), 0.05 g of  zeolite, and 10 ml of Cr3+ solutions with different concentrations. The experiments were performed in closed flasks at  room temperature (25 +- 2⁰ C) in duplicate, pH values (Mettler Toledo, pH-meter) were monitored at each sample  withdrawal. Isotherm data were obtained after reaching an equilibrium time of 24 h. All samples were filtered using a  membrane of 0.45 m pore size prior to measurements of Cr3+ concentrations by ICP-MS (Perkin Elmer ICP-MS, Optima  8300). The adsorption capacity (qe) of zeolite was calculated by Eq. (1) where C0 and Cf are the initial and final metal ion  concentrations, respectively, Va is the aqueous phase volume and M is the weight of zeolite used.


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