资料摘要
资料下载研究领域:燃料电池质子导电膜 交流阻抗频率范围:1MHz - 1mHz By grafting 4-vinylpyridine (4VP), N-vinylformamide (NVF), and 1-vinylimidazole (1VIm) onto electron beam irradiated ETFE and FEP films, the basic membrane matrices ETFE-graftpoly( 4VP), FEP-graft-poly(4VP), ETFE-graft-poly(1VIm), and ETFE-graft-poly(vinylamine), after subsequent hydrolysis of ETFE-graft-poly(NVF), can be obtained. These matrices are doped with phosphoric acid to produce acid–base composite materials that exhibit high proton conductivities up to 100 mScm1 at high temperatures (120 8C) and no humidification. The produced membranes are robust, flexible, and mechanically stable even at high doping levels and endure temperatures of up to 160 8C. Preliminary tests in H2/O2 fuel cells provide power densities between 75 and 150 mAcm2 at 120 8C without humidification. C. Schmidt, G. Schmidt-Naake Institut fu¨r Technische Chemie, Technische Universita¨t Clausthal, Erzstra?e 18, 38678 Clausthal-Zellerfeld, Germany Fax: (t49) 5323 72 3655; E-mail: gudrun.schmidt@tu-clausthal.de 1164 Macromol. Mater. Eng. 2007, 292, 1164–1175 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim DOI: 10.1002/mame.200700188
染料敏化太阳能电池DSSC
简介:Investigation on photovolatic performance of hollow sphere/nanoparticle composite TiO2 electrodes for solid state dye sensitized solar cells. Dynamic Response of Charge Transfer and Recombination at Various Electrodes in Dye-sensitized Solar Cells Investigated Using Intensity Modulated Photocurrent and Photovoltage Spectroscopy.
锂离子电池电解质
简介:Nature SR-JLU-Integrated Solid-Nanoporous Copper-Oxide Hybrid Bulk Electrodes for High-performance Lithium-Ion Batteries
阻抗文献7
简介:Performance of non-porous graphite and titanium-based anodes in microbial fuel cells
阻抗文献6
简介:Influence of CO2 on ionic conductivity of anion exchange membrane for alkaline DMFCs
阻抗文献5燃料电池
简介:Electrochemical impedance spectroscopy (EIS) is in potential a powerful tool for the in depth analysis of microbial fuels cells (MFCs). To prevent the risk of drawing false conclusions from invalid EIS measurements we investigated the feasibility of this method on an MFC by checking: linearity, causality, stability and finiteness. EIS application under steady state conditions was partly feasible. For further application EIS on MFCs we recommend to: (1) use the constant anode or cathode potential measurement mode with a fast couple at the counter electrode; (2) record the polarization curve and measure at different amplitudes to check the linearity condition; (3) perform preliminary measurements to reveal measurement presets; (4) apply prolonged pretreatment to facilitate the stability criterion; (5) perform duplicate measurements to examine the stability; (6) use a broad frequency range to validate the finiteness criterion; (7) use a statistical based validation check based on the Kramers-Kronig transformation.
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