资料摘要
资料下载研究领域：SOFC燃料电池 方法：IV特性和交流阻抗 范围：1MHz - 0.1Hz The present work aims to explore the activity of Cu/CeO2 composites as anodic electrodes in direct iso-octane SOFCs. When the cell was operated as a membrane reactor, the effect of temperature, Pi-C8H18 and applied anodic overpotentials on the electrocatalytic activity and products' distribution, at both open and closed circuit conditions, was examined. Additionally, in situ DRIFT spectroscopy was carried out in order to correlate the performance of Cu/CeO2 with its surface chemistry during iso-octane decomposition. Under the “fuel cell” mode of operation, the electrochemical performance and stability of Cu/CeO2 were investigated by voltage–current density–power density and AC impedance measurements. The results reveal that at high anodic polarization conditions, carbon formation can be noticeably restricted (verified also by EDAX analysis), while H2 production was enhanced due to partial oxidation, steam reforming, dehydrogenation and water gas shift reactions. Achieved power densities were found to substantially increase both with temperature and Pi-C8H18, while minor performance degradation was indicated in the step-change tests, where the overall activity of Cu–CeO2 electrodes remained essentially unaffected.
文献贡献者
染料敏化太阳能电池DSSC
简介：Investigation on photovolatic performance of hollow sphere/nanoparticle composite TiO2 electrodes for solid state dye sensitized solar cells. Dynamic Response of Charge Transfer and Recombination at Various Electrodes in Dye-sensitized Solar Cells Investigated Using Intensity Modulated Photocurrent and Photovoltage Spectroscopy.
锂离子电池电解质
简介：Nature SR-JLU-Integrated Solid-Nanoporous Copper-Oxide Hybrid Bulk Electrodes for High-performance Lithium-Ion Batteries
阻抗文献7
简介：Performance of non-porous graphite and titanium-based anodes in microbial fuel cells
阻抗文献6
简介：Influence of CO2 on ionic conductivity of anion exchange membrane for alkaline DMFCs
阻抗文献5燃料电池
简介：Electrochemical impedance spectroscopy (EIS) is in potential a powerful tool for the in depth analysis of microbial fuels cells (MFCs). To prevent the risk of drawing false conclusions from invalid EIS measurements we investigated the feasibility of this method on an MFC by checking: linearity, causality, stability and finiteness. EIS application under steady state conditions was partly feasible. For further application EIS on MFCs we recommend to: (1) use the constant anode or cathode potential measurement mode with a fast couple at the counter electrode; (2) record the polarization curve and measure at different amplitudes to check the linearity condition; (3) perform preliminary measurements to reveal measurement presets; (4) apply prolonged pretreatment to facilitate the stability criterion; (5) perform duplicate measurements to examine the stability; (6) use a broad frequency range to validate the finiteness criterion; (7) use a statistical based validation check based on the Kramers-Kronig transformation.
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