资料摘要
资料下载研究领域:离子液体 测量方法:交流阻抗 The physicochemical properties of two novel ionic liquids based on benzyltriethylphosphonium and benzyltributylphosphonium cations are described in this report. It was found that both benzyl-substituted phosphonium cations gave low-melting salts in combination with a bis(trifluoromethylsulfonyl)amide anion. The thermogravimetric analysis suggested that the benzyl-substituted phosphonium ionic liquids showed higher thermal stability than those of not only the alkyl-substituted phosphonium ILs but also the corresponding benzyl-substituted ammonium compounds. The benzyl-substituted phosphonium ionic liquids also exhibited relatively high conductivities when compared to those of the corresponding ammonium compounds. These results indicate an improving effect of introducing a benzyl group into the phosphonium cations on both the thermal stability and the conductivity.
染料敏化太阳能电池DSSC
简介:Investigation on photovolatic performance of hollow sphere/nanoparticle composite TiO2 electrodes for solid state dye sensitized solar cells. Dynamic Response of Charge Transfer and Recombination at Various Electrodes in Dye-sensitized Solar Cells Investigated Using Intensity Modulated Photocurrent and Photovoltage Spectroscopy.
锂离子电池电解质
简介:Nature SR-JLU-Integrated Solid-Nanoporous Copper-Oxide Hybrid Bulk Electrodes for High-performance Lithium-Ion Batteries
阻抗文献7
简介:Performance of non-porous graphite and titanium-based anodes in microbial fuel cells
阻抗文献6
简介:Influence of CO2 on ionic conductivity of anion exchange membrane for alkaline DMFCs
阻抗文献5燃料电池
简介:Electrochemical impedance spectroscopy (EIS) is in potential a powerful tool for the in depth analysis of microbial fuels cells (MFCs). To prevent the risk of drawing false conclusions from invalid EIS measurements we investigated the feasibility of this method on an MFC by checking: linearity, causality, stability and finiteness. EIS application under steady state conditions was partly feasible. For further application EIS on MFCs we recommend to: (1) use the constant anode or cathode potential measurement mode with a fast couple at the counter electrode; (2) record the polarization curve and measure at different amplitudes to check the linearity condition; (3) perform preliminary measurements to reveal measurement presets; (4) apply prolonged pretreatment to facilitate the stability criterion; (5) perform duplicate measurements to examine the stability; (6) use a broad frequency range to validate the finiteness criterion; (7) use a statistical based validation check based on the Kramers-Kronig transformation.
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