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  • 我在故我思

    第36楼2008/04/30

    这个应该是这样的:楼主给的资料中:LOD是指的limit of detection、LOQ是指的limit of quantification,在第二章幻灯片中说明了:“LOQ:定量限、测定限”;而在欧盟资料中“LOQ--Limit of quantitation (quantification) (also known as limit of determination, LOD)”阐述的是“Limit of quantitation (quantification)=limit of determination”,即LOQ=LOD,这也是和楼主的资料中的“LOQ:定量限、测定限”是一致的;由于“limit of determination”和“limit of detection ”的缩写都是LOD,所以上文中提出“LOQ is preferable to LOD because it avoids possible con-fusion with "limit of detection"”。

    sunrain001 发表:有一个问题,在欧盟METHOD VALIDATION AND QUALITY CONTROL PROCEDURES FOR PESTICIDE RESIDUES ANALYSIS IN FOOD AND FEED 文件中,认为LOD与LOQ是一个东西--定量测定限,检出限用limit of detection 表示,LOD是limit of determination,原文释义如下:LOQ--Limit of quantitation (quantification) (also known as limit of determination, LOD). The minimum concentration or mass of the analyte that can be quantified with acceptable accuracy and precision. Should apply to the complete analytical method. Variously defined but must be a value greater than the limit of detection. With most methods and determination systems, the LOQ has no fixed value. LOQ is preferable to LOD because it avoids possible con-fusion with “limit of detection”. However, in legislation MRLs that are set at the limit of quantification/determination are referred to as “LOD MRLs”, not“LOQ MRLs”.

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  • cghy001

    第37楼2008/12/01

    请问Sy/x,以及最后LOD=t0.99*0.0011式中t0.99是查什么表得到的?请不吝赐教。

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  • cghy001

    第38楼2008/12/01

    本人已知道答案.

    具体如下:

    Sy.x为剩余标准偏差,即扣除X值对Y值的影响后的标准偏差

    Sy.x=SQR((y-yhat)2/5-2)

    剩余标准偏差在测量仪器精密性方面比标准偏差和变异系数更加科学准确.

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  • yanyiyang

    第39楼2008/12/01

    恩,过来学习一下的。

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  • 我在故我思

    第40楼2009/01/28

    你好!t0.99是在Student表中(即t值表)根据置信度和自由度查出来的。

    cghy001 发表:请问Sy/x,以及最后LOD=t0.99*0.0011式中t0.99是查什么表得到的?请不吝赐教。

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  • luyongxian

    第41楼2009/01/29

    国内计算方法检出限MDL的时候一般都是用的t值。

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  • 颠三倒四

    第43楼2009/08/14

    贡献这么好的资料,真是太感谢了

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  • liangjiapeng

    第45楼2009/12/29

    正在学习这块知识,很有用,谢谢!

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