方案摘要
方案下载应用领域 | 其他 |
检测样本 | 其他 |
检测项目 | |
参考标准 | 暂无 |
The orientation, structure, and energetics of the vapor/acetone-water interface are studied with sum frequency generation vibrational spectroscopy (SFG-VS). We used the polarization null angle (PNA) method in SFGVS to accurately determine the interfacial acetone molecule orientation, and we found that the acetone molecule has its CdO group pointing into bulk phase, one CH3 group pointing up from the bulk, and the other CH3 group pointing into the bulk phase. This well-ordered interface layer induces an antiparallel structure in the second layer through dimer formation from either dipolar or hydrogen bond interactions. With a double-layer adsorption model (DAM) and Langmuir isotherm, the adsorption free energies for the first and second layer are determined as ¢G°ads,1 ) - 1.9 ( 0.2 kcal /mol and ¢G°ads,2 ) - 0.9 ( 0.2 kcal /mol, respectively. Since ¢G°ads,1 is much larger than the thermal energy kT ) 0.59 kcal /mol, and ¢G°ads,2 is close to kT, the second layer has to be less ordered. Without either strong dipolar or hydrogen bonding interactions between the second and the third layer, the third layer should be randomly thermalized as in the bulk liquid. Therefore, the thickness of the interface is not more than two layers thick. These results are consistent with previous MD simulations for the vapor/pure acetone interface, and undoubtedly provide direct microscopic structural evidences and new insight for the understanding of liquid and liquid mixture interfaces. The experimental techniques and quantitative analysis methodology used for detailed measurement of the liquid mixture interfaces in this report can also be applied to liquid interfaces, as well as other molecular interfaces in general.
在一个双稳湍流涡旋火焰中,对间歇性动态的时间-频率定位
Particle-laden Taylor-Couette流:高阶转变和径向局部波浪涡旋的证据
7根杆束的流体-结构相互作用:用实验数据对比数值模拟
相关产品
汽车光学检测系统AIS
PT403型波长可调谐皮秒激光器
ANL系列高能量高重复频率DPSS纳秒激光器
APL4206 系列高能量皮秒激光放大器
UltraFlux FF/FT 5000 高能量可调谐飞秒激光器系统
UltraFlux FT300型波长可调谐飞秒激光器系统
Ekspla 超高功率激光器系统SYLOS 2A
LaVision PTUx 可编程时间控制单元
LaVision 用于粒子成像测速PIV的相机
LaVision StrainMaser 全场应变测试系统组件
LaVision 用于数字图像相关DIC的相机
LaVision StrainMaster 数字图像相关分析软件包
LaVision 标定板
LaVision StrainMaster 形变应变成像测量系统
LaVision StrainMaster DVC 体视全场应变测量系统
关注
拨打电话
留言咨询