方案摘要
方案下载应用领域 | 食品/农产品 |
检测样本 | 其他食品 |
检测项目 | 农药残留>除草剂, 其他, 有机磷杀虫剂 |
参考标准 | GB 23200.121-2021 |
GB 23200.121-2021 食品安全国家标准 《植物源性食品中331种农药及其代谢物残留量的测定 液相色谱—质谱联用法》已正式实施,此标准采用QuEChERS前处理方法、液相色谱-三重四极杆串联质谱一次进样正负源切换同时测定331种农药及其代谢物残留量,解决了现行液质标准适用农产品基质种类少、农药及代谢物品种不全、前处理操作复杂、部分农药方法定量限高于最大残留限量等诸多问题。本文分别以杏鲍菇、上海青、大豆、红茶为植源性样品基质,选取了国标GB23200.121-2021中的164种农药,采用纳谱分析的SelectCore QuEChERS萃取盐包及净化管分别对样品基质进行前处理,使用超高效三重四级杆液相色谱-质谱联用仪进行测定,实验数据表明纳谱分析的SelectCore QuEChERS前处理产品可以有效避免基质杂质干扰,并且实验结果稳定,回收率满足检测要求。
中文名 | 食用菌(杏鲍菇) | 深色蔬菜(上海青) | 油料(大豆) | 茶叶(红茶) | ||||
回收率% | RSD% | 回收率% | RSD% | 回收率% | RSD% | 回收率% | RSD% | |
杀线威肟 | 103% | 11% | 95% | 10% | 99% | 10% | 144% | 5% |
丙炔噁草酮 | 89% | 5% | 90% | 4% | 98% | 10% | 110% | 10% |
乙拌磷亚砜 | 129% | 4% | 113% | 6% | 105% | 6% | 110% | 3% |
倍硫磷砜 | 85% | 10% | 108% | 7% | 81% | 11% | 108% | 16% |
氟啶虫胺腈 | 103% | 5% | 99% | 3% | 114% | 2% | 108% | 4% |
残杀威 | 125% | 2% | 132% | 3% | 141% | 5% | 107% | 3% |
恶虫威 | 124% | 3% | 135% | 5% | 137% | 3% | 106% | 2% |
氯唑磷 | 108% | 4% | 110% | 4% | 117% | 2% | 105% | 10% |
氰草津 | 94% | 5% | 106% | 3% | 101% | 4% | 105% | 7% |
氟噻草胺 | 109% | 4% | 101% | 1% | 107% | 4% | 104% | 10% |
四氟醚唑 | 92% | 3% | 104% | 11% | 104% | 4% | 104% | 6% |
亚砜磷 | 102% | 3% | 97% | 1% | 103% | 4% | 103% | 4% |
乙拌磷砜 | 101% | 6% | 125% | 4% | 94% | 4% | 103% | 3% |
氟酰脲 | 87% | 7% | 104% | 7% | 97% | 6% | 102% | 2% |
噻虫啉 | 92% | 11% | 104% | 2% | 108% | 3% | 102% | 5% |
噻唑磷 | 106% | 3% | 108% | 1% | 112% | 3% | 101% | 5% |
咯菌腈 | 143% | 26% | 109% | 24% | 91% | 24% | 101% | 12% |
苯酰菌胺 | 104% | 4% | 105% | 2% | 102% | 3% | 101% | 8% |
咪唑菌酮 | 101% | 5% | 101% | 1% | 91% | 2% | 101% | 5% |
莠去津 | 93% | 5% | 106% | 2% | 97% | 5% | 101% | 3% |
甲氧虫酰肼 | 102% | 5% | 106% | 3% | 101% | 5% | 100% | 2% |
西玛津 | 93% | 6% | 105% | 3% | 98% | 6% | 100% | 6% |
啶氧菌酯 | 102% | 6% | 108% | 5% | 117% | 4% | 100% | 4% |
噻虫胺 | 100% | 7% | 96% | 2% | 108% | 9% | 100% | 9% |
氯噻啉 | 95% | 4% | 99% | 5% | 109% | 4% | 100% | 5% |
氟虫脲 | 91% | 4% | 99% | 2% | 92% | 5% | 100% | 5% |
甲磺草胺 | 110% | 12% | 112% | 4% | 100% | 7% | 100% | 4% |
猛杀威 | 114% | 3% | 118% | 4% | 113% | 5% | 100% | 3% |
鱼藤酮 | 97% | 3% | 92% | 2% | 99% | 8% | 99% | 6% |
脱甲基-甲酰氨基-抗蚜威 | 129% | 4% | 125% | 8% | 134% | 4% | 99% | 1% |
氧丰索磷砜 | 102% | 3% | 102% | 3% | 110% | 5% | 99% | 6% |
绿麦隆 | 102% | 7% | 107% | 2% | 109% | 6% | 98% | 3% |
腈苯唑 | 93% | 5% | 95% | 3% | 102% | 5% | 98% | 2% |
甲基二磺隆 | 51% | 11% | 59% | 8% | 78% | 10% | 98% | 1% |
苯硫威 | 113% | 4% | 112% | 2% | 114% | 5% | 98% | 5% |
内吸磷 | 106% | 4% | 114% | 2% | 119% | 2% | 98% | 5% |
敌草胺 | 108% | 4% | 103% | 3% | 112% | 6% | 98% | 3% |
特丁津 | 104% | 3% | 113% | 5% | 105% | 4% | 98% | 6% |
马拉氧磷 | 97% | 6% | 117% | 5% | 93% | 6% | 97% | 4% |
氰霜唑 | 96% | 6% | 102% | 2% | 110% | 3% | 97% | 6% |
啶酰菌胺 | 89% | 6% | 101% | 2% | 101% | 4% | 97% | 3% |
螺虫乙酯 | 79% | 11% | 70% | 3% | 77% | 4% | 97% | 2% |
噁草酮 | 93% | 5% | 99% | 4% | 99% | 7% | 97% | 4% |
环酰菌胺 | 96% | 9% | 109% | 5% | 120% | 5% | 97% | 3% |
杀铃脲 | 111% | 4% | 105% | 1% | 115% | 6% | 97% | 4% |
吡草醚 | 95% | 4% | 111% | 4% | 96% | 6% | 97% | 0% |
稻瘟灵 | 106% | 3% | 112% | 1% | 110% | 4% | 97% | 4% |
异丙隆 | 111% | 5% | 120% | 1% | 125% | 2% | 96% | 3% |
苯嘧磺草胺 | 71% | 9% | 72% | 2% | 101% | 5% | 96% | 3% |
磷胺 | 99% | 3% | 113% | 1% | 101% | 7% | 96% | 2% |
丁草胺 | 103% | 6% | 129% | 1% | 124% | 5% | 96% | 3% |
乙羧氟草醚 | 92% | 2% | 105% | 4% | 119% | 2% | 96% | 6% |
速灭威 | 122% | 3% | 141% | 3% | 114% | 5% | 95% | 4% |
缬霉威 | 103% | 5% | 101% | 1% | 104% | 4% | 95% | 3% |
异噁草酮 | 98% | 2% | 124% | 8% | 91% | 4% | 95% | 1% |
醚苯磺隆 | 54% | 9% | 73% | 15% | 90% | 6% | 95% | 2% |
丰索磷砜 | 90% | 6% | 103% | 6% | 85% | 8% | 95% | 1% |
甲基毒死蜱 | 96% | 8% | 96% | 2% | 98% | 7% | 95% | 10% |
仲丁威 | 105% | 4% | 120% | 5% | 97% | 3% | 94% | 1% |
苯螨特 | 91% | 4% | 89% | 1% | 85% | 5% | 94% | 2% |
嗪草酸甲酯 | 87% | 4% | 94% | 1% | 88% | 4% | 94% | 1% |
氟铃脲 | 86% | 5% | 90% | 2% | 105% | 7% | 94% | 3% |
戊唑醇 | 96% | 2% | 98% | 1% | 104% | 2% | 93% | 0% |
喹禾灵(乙酯) | 101% | 3% | 101% | 2% | 100% | 6% | 93% | 5% |
哌草丹 | 128% | 4% | 133% | 3% | 110% | 5% | 93% | 9% |
苄草丹 | 119% | 5% | 133% | 5% | 114% | 6% | 93% | 4% |
醚磺隆 | 52% | 8% | 64% | 6% | 92% | 3% | 93% | 4% |
氟酮唑草 | 101% | 2% | 96% | 2% | 107% | 3% | 93% | 3% |
亚胺硫磷 | 102% | 10% | 105% | 2% | 107% | 6% | 93% | 4% |
甲基立枯磷 | 97% | 8% | 105% | 8% | 98% | 7% | 92% | 1% |
苯硫磷 | 97% | 4% | 101% | 8% | 82% | 9% | 92% | 4% |
喹硫磷 | 88% | 4% | 108% | 2% | 89% | 5% | 92% | 3% |
双炔酰菌胺 | 97% | 4% | 112% | 5% | 92% | 4% | 92% | 1% |
氟啶虫酰胺 | 88% | 5% | 102% | 2% | 86% | 6% | 92% | 1% |
噁唑菌酮 | 104% | 17% | 112% | 3% | 100% | 4% | 92% | 15% |
倍硫磷亚砜 | 107% | 7% | 112% | 4% | 102% | 6% | 92% | 3% |
百治磷 | 104% | 3% | 112% | 3% | 97% | 5% | 92% | 1% |
久效磷 | 103% | 6% | 114% | 7% | 99% | 4% | 92% | 3% |
哒嗪硫磷 | 103% | 4% | 114% | 4% | 96% | 2% | 92% | 2% |
杀线威 | 113% | 5% | 129% | 4% | 115% | 3% | 91% | 4% |
敌稗 | 98% | 2% | 110% | 2% | 95% | 4% | 91% | 3% |
氟硅唑 | 96% | 3% | 110% | 4% | 96% | 4% | 91% | 2% |
乙虫清 | 99% | 4% | 114% | 2% | 85% | 2% | 91% | 3% |
恶嗪草酮 | 104% | 1% | 102% | 2% | 99% | 3% | 91% | 2% |
苯霜灵 | 99% | 1% | 111% | 4% | 90% | 6% | 91% | 1% |
噻呋酰胺 | 101% | 5% | 121% | 4% | 104% | 8% | 91% | 4% |
稻丰散 | 100% | 6% | 101% | 2% | 89% | 5% | 91% | 12% |
种菌唑 | 93% | 5% | 92% | 3% | 101% | 12% | 91% | 5% |
炔苯酰草胺 | 121% | 5% | 136% | 5% | 116% | 2% | 91% | 5% |
呋线威 | 100% | 4% | 119% | 4% | 90% | 5% | 90% | 0% |
吡噻菌胺 | 98% | 3% | 106% | 3% | 99% | 5% | 90% | 3% |
苯氧威 | 98% | 5% | 117% | 5% | 102% | 3% | 90% | 3% |
苄氯三唑醇 | 93% | 3% | 96% | 3% | 98% | 4% | 90% | 1% |
异恶唑草酮 | 82% | 4% | 99% | 6% | 67% | 5% | 90% | 8% |
乳氟禾草灵 | 102% | 3% | 137% | 1% | 98% | 3% | 90% | 5% |
茚虫威 | 97% | 5% | 111% | 1% | 92% | 9% | 90% | 4% |
醚菌酯 | 102% | 4% | 125% | 3% | 100% | 4% | 90% | 2% |
嗪草酮 | 97% | 4% | 135% | 3% | 110% | 4% | 90% | 5% |
异丙草胺 | 103% | 4% | 135% | 4% | 110% | 5% | 90% | 5% |
氟唑环菌胺 | 96% | 5% | 116% | 5% | 93% | 5% | 90% | 2% |
E-烯啶虫胺 | 91% | 5% | 99% | 3% | 104% | 5% | 90% | 40% |
丰索磷 | 107% | 3% | 110% | 3% | 98% | 6% | 90% | 2% |
戊菌唑 | 99% | 5% | 110% | 4% | 97% | 5% | 90% | 4% |
乙氧氟草醚 | 81% | 5% | 88% | 3% | 100% | 6% | 90% | 6% |
吡氟酰草胺 | 93% | 6% | 113% | 4% | 93% | 8% | 90% | 4% |
双氟磺草胺 | 53% | 9% | 62% | 6% | 65% | 2% | 90% | 1% |
炔螨特 | 103% | 4% | 138% | 2% | 84% | 2% | 90% | 1% |
苄嘧磺隆 | 60% | 12% | 95% | 2% | 94% | 4% | 89% | 0% |
乙嘧酚磺酸酯 | 103% | 2% | 101% | 2% | 103% | 4% | 89% | 4% |
唑虫酰胺 | 101% | 6% | 103% | 2% | 99% | 4% | 89% | 5% |
氯嘧磺隆 | 51% | 11% | 62% | 2% | 66% | 2% | 89% | 0% |
野麦畏 | 94% | 4% | 94% | 3% | 72% | 8% | 89% | 7% |
氟苯脲 | 84% | 9% | 91% | 4% | 78% | 10% | 89% | 2% |
霜脲氰 | 89% | 6% | 108% | 2% | 89% | 6% | 88% | 3% |
环丙唑醇 | 70% | 3% | 103% | 2% | 92% | 5% | 88% | 5% |
虱螨脲 | 86% | 5% | 104% | 1% | 85% | 9% | 88% | 5% |
西草净 | 97% | 3% | 116% | 5% | 91% | 5% | 88% | 4% |
氯草敏 | 96% | 7% | 119% | 4% | 91% | 5% | 88% | 3% |
甲基嘧啶磷 | 96% | 3% | 113% | 4% | 86% | 6% | 88% | 1% |
保棉磷 | 104% | 7% | 128% | 4% | 106% | 7% | 87% | 1% |
氟菌唑 | 91% | 2% | 104% | 1% | 89% | 7% | 87% | 2% |
敌瘟磷 | 100% | 3% | 113% | 3% | 81% | 5% | 87% | 3% |
氟唑菌酰胺 | 93% | 4% | 109% | 2% | 96% | 7% | 87% | 3% |
禾草敌 | 111% | 6% | 108% | 7% | 95% | 7% | 87% | 2% |
唑嘧菌胺 | 86% | 5% | 100% | 1% | 100% | 5% | 87% | 7% |
叶菌唑 | 93% | 4% | 101% | 3% | 97% | 7% | 87% | 6% |
丙环唑 | 88% | 3% | 111% | 2% | 80% | 1% | 87% | 2% |
吡丙醚 | 105% | 4% | 105% | 2% | 89% | 4% | 86% | 4% |
乙氧磺隆 | 53% | 14% | 43% | 4% | 45% | 5% | 86% | 4% |
己唑醇 | 92% | 5% | 124% | 4% | 84% | 5% | 86% | 1% |
利谷隆 | 99% | 8% | 109% | 2% | 100% | 8% | 86% | 3% |
氟吡草胺 | 94% | 5% | 103% | 1% | 97% | 5% | 86% | 5% |
酰嘧磺隆 | 64% | 10% | 52% | 2% | 46% | 6% | 86% | 4% |
甲氰菊酯 | 94% | 6% | 105% | 5% | 74% | 11% | 86% | 3% |
地虫硫磷 | 96% | 6% | 112% | 4% | 79% | 6% | 86% | 5% |
硫线磷 | 113% | 3% | 137% | 3% | 102% | 7% | 86% | 2% |
氯吡嘧磺隆 | 75% | 21% | 58% | 5% | 42% | 2% | 85% | 6% |
抑霉唑 | 94% | 5% | 99% | 2% | 97% | 8% | 85% | 7% |
螺螨酯 | 84% | 5% | 109% | 4% | 67% | 4% | 85% | 2% |
吡唑醚菌酯 | 92% | 3% | 118% | 2% | 87% | 1% | 85% | 2% |
烯唑醇 | 88% | 4% | 87% | 3% | 96% | 0% | 85% | 3% |
呋虫胺 | 112% | 22% | 78% | 9% | 109% | 4% | 85% | 19% |
仲丁灵 | 100% | 6% | 118% | 6% | 79% | 7% | 84% | 1% |
咪鲜胺 | 99% | 4% | 96% | 3% | 105% | 3% | 84% | 4% |
亚胺唑 | 88% | 4% | 102% | 4% | 87% | 5% | 84% | 3% |
苯醚甲环唑 | 90% | 3% | 107% | 1% | 82% | 2% | 84% | 2% |
内吸磷-S-甲基-砜 | 100% | 4% | 144% | 8% | 108% | 5% | 83% | 2% |
乙氧呋草黄 | 97% | 14% | 110% | 9% | 136% | 12% | 83% | 3% |
烯效唑 | 96% | 4% | 112% | 5% | 90% | 5% | 82% | 7% |
甲磺隆 | 40% | 13% | 42% | 3% | 53% | 2% | 80% | 3% |
联苯三唑醇 | 96% | 4% | 126% | 3% | 94% | 8% | 79% | 3% |
噻苯隆 | 41% | 9% | 109% | 5% | 70% | 6% | 78% | 7% |
四螨嗪 | 88% | 14% | 99% | 3% | 20% | 11% | 77% | 3% |
醚菊酯 | 99% | 5% | 136% | 4% | 55% | 2% | 75% | 2% |
丁苯吗啉 | 96% | 4% | 109% | 2% | 72% | 5% | 75% | 4% |
喹螨醚 | 87% | 3% | 115% | 3% | 71% | 4% | 74% | 1% |
乙拌磷 | 97% | 10% | 115% | 8% | 117% | 8% | 74% | 7% |
乙嘧酚 | 69% | 7% | 83% | 1% | 90% | 2% | 72% | 5% |
苯锈啶 | 100% | 2% | 112% | 2% | 86% | 6% | 68% | 1% |
甲基硫菌灵 | 58% | 4% | 108% | 5% | 90% | 8% | 64% | 5% |
噻苯哒唑 | 55% | 11% | 120% | 5% | 82% | 2% | 63% | 3% |
生物苄呋菊酯 | 54% | 6% | 97% | 2% | 63% | 4% | 62% | 5% |
霜霉威盐酸盐 | 92% | 3% | 91% | 5% | 82% | 1% | 50% | 3% |
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