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【资料】Spectroscopy of Pharmaceutical Solids

同位素及其它无机质谱

  • 主编:Harry G. Brittain
    目录:Part I. Introduction to Spectroscopy
    1. Electromagnetic Radiation and Spectroscopy . . . . . . . . . . . . . . . . 1
    Harry G. Brittain
    Nature of Electromagnetic Radiation . . . . 1
    Classical Description of Electromagnetic Radiation . . . . 3
    The Quantum Theory of Electromagnetic Radiation . . . . 8
    Ionization and Excitation of Atoms . . . . 12
    Development of the Quantum Theory . . . . 17
    Overview of Spectroscopy . . . . 28
    Summary . . . . 30
    References . . . . 31
    Part II. Core Electron Spectroscopy
    2. Core Electron States and X-Ray Absorption Spectroscopy . . . . . 33
    Harry G. Brittain
    Wave Mechanical Description of the Hydrogen Atom . . . . 33
    X-Ray Absorption Spectroscopy . . . . 53
    References . . . . 64
    3. X-Ray Photoelectron and X-Ray Fluorescence Spectroscopy . . . 67
    Harry G. Brittain
    X-Ray Emission Spectroscopies . . . . 67
    X-Ray Photoelectron Spectroscopy . . . . 69
    X-Ray Fluorescence Spectroscopy . . . . 77
    References . . . . 87
    Part III. Valence Electron Spectroscopy
    4. Molecular Orbital Theory and the Electronic Structure
    of Molecules . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
    Harry G. Brittain
    Molecular Orbital (MO) Theory of Organic Molecules . . . . 91
    LCAO-MO Theory . . . . 93
    LCAO-MO Theory and the Spectroscopy of
    Diatomic Molecules . . . . 97
    MO Theory and the Spectroscopy of Polyatomic Molecules . . . . 104
    General Features of the Absorption
    Spectroscopy of Organic Molecules . . . . 112
    References . . . . 119
    5. UV/VIS Reflectance Spectroscopy . . . . . . . . . . . . . . . . . . . . . . 121
    Harry G. Brittain
    Introduction . . . . 121
    Categories of Light Reflectance . . . . 122
    Theory Associated with Diffuse Reflectance Measurements . . . . 124
    Instrumentation for the Measurement of Diffuse Reflectance . . . . 127
    Quantitative Measurement of Color . . . . 129
    Applications of UV/VIS Diffuse Reflectance Spectroscopy
    to the Study of Solids Having Pharmaceutical Interest . . . . 134
    Use of Adsorbed Indicators for the Evaluation
    of Surface Acidity and Basicity . . . . 141
    Summary . . . . 147
    References . . . . 147
    6. Luminescence Spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . . 151
    Harry G. Brittain
    Introduction . . . . 151
    Photophysical Processes in Isolated Organic Molecules . . . . 152
    Photophysical Processes Associated with
    Interacting Molecules . . . . 157
    Instrumentation for the Measurement of Luminescence
    Spectra . . . . 170
    Photoluminescence and the Structure of
    Organic Molecules . . . . 178
    Studies of Luminescence in the Crystalline State . . . . 179
    Photoluminescence from Molecules Adsorbed on Surfaces . . . . 184
    References . . . . 198
    Part IV. Vibrational Level Spectroscopy
    7. Molecular Motion and Vibrational Spectroscopy . . . . . . . . . . . 205
    Harry G. Brittain
    Introduction . . . . 205
    Motion of Nuclei in Molecules . . . . 206
    Rotation and Vibration in Diatomic Molecules . . . . 210
    Vibrational Energy Levels and Spectroscopy of
    Diatomic Molecules . . . . 213
    Vibrational Energy Levels and Spectroscopy of the
    Fundamental Transitions of Polyatomic Molecules . . . . 219
    Spectroscopy of Transitions Associated with Overtones and
    Combinations of Fundamental Vibrational Modes . . . . 227
    Summary . . . . 231
    References . . . . 232
    8. Infrared Absorption Spectroscopy . . . . . . . . . . . . . . . . . . . . . . 235
    David E. Bugay and Harry G. Brittain
    Introduction . . . . 235
    Some Fundamental Principles of IR Absorption Spectroscopy . . . . 236
    Instrumentation for the Measurement of
    IR Spectra in the Solid State . . . . 239
    Applications of IR Spectroscopy to Areas of
    Pharmaceutical Interest . . . . 246
    References . . . . 265
    9. Raman Spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271
    David E. Bugay and Harry G. Brittain
    Introduction . . . . 271
    Some Fundamental Principles of the Raman Effect . . . . 272
    Instrumentation for Measurement of Raman
    Spectra in the Solid State . . . . 278
    Group Frequency Correlations in Raman Spectroscopy
    and Effects of the Solid State . . . . 283
    Applications of Raman Spectroscopy to
    Areas of Pharmaceutical Interest . . . . 286
    References . . . . 309
    10. Near-Infrared Spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . . 313
    Robert P. Cogdill and James K. Drennen, III
    Introduction . . . . 313
    Fundamental Principles . . . . 315
    Practice of NIR Spectroscopy . . . . 344
    Applications in Pharmaceutical Solids Analysis . . . . 389
    References . . . . 406
    Part V. Nuclear Spin Level Spectroscopy
    11. Solid-State Nuclear Magnetic Resonance Spectrometry . . . . . . 413
    Ales Medek
    Fundamental Principles of NMR . . . . 413
    SSNMR of Powder Solids . . . . 420
    Pharmaceutically Relevant Applications of SSNMR . . . . 427
    References . . . . 538
    Spectroscopy of Pharmaceutical Solids
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  • gevy

    第1楼2008/05/07

    是个好贴,不过看不懂,刚如行,名词看不懂的。

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