AQF-2100H裂解燃烧离子色谱法如何满足电子电器产品中关于无卤的环保要求-国际标准JPCA

三菱仪器

2022/10/09

私聊

环保指令综合讨论

AQF-2100H
Advanced,developed to the second generation.Powerful,fast solution for sulfur and halogen (Chlorine,Fluorine,Bromine,Iodine)analysis.
先进的第二代自动快速燃烧裂解吸收离子色谱系统，快速、可靠、准确的分析样品中的硫和卤素（F,Cl,Br,I)

Features产品特点

SKILL FREE OPERATION无障碍操作
Thanks to the new combustion program and double tube system,sample can now be combusted surely and safely without special skill and training.Sample combustion can be completed in as short as 5 min.
由于新的燃烧程序和双裂解管系统，样品燃烧的更加彻底和安全，完全燃烧的时间短至5分钟。
New developed unique combustion method can be applied for various samples,e.g. Heavy matrix,different pyrolysis temperature of elements,and even to completely unknown samples.This program can also enable larger amount of sample up to 150mg.
新研发的独一无二的燃烧方法可以应用于各种的样品。比如：重基质样品，不同裂解温度的元素，及未知样品的完全燃烧。同时这套程序可以燃烧重达150mg的样品。
PYROHYDROLYTIC COMBUSTION SYSTEM 高温裂解燃烧系统
Controlled pyrohydrolytic combustion enables highly accurate analysis of Fluorine,high concentration Chlorine,and Bromine.
控制高温裂解燃烧使精确分析F，Cl，Br成为可能
HIGH SENSITIVE ANALYSIS高灵敏分析
Thanks to dedicated gas controller unit,extremely low gas blank is realized.
精确的气体控制单元，使得气体空白更低。
By utilizing high purity quartz tube,trace analysis can be applicable.
高纯度的石英管，更适用于痕量分析。
ABSORBENT CORRECTION 吸收液修正
Constant volume function enables high accurate analysis and easier operation.Since there is no longer need to use internal standards,samples with complex matrix can be measured.
定容功能的使用使得分析更加精确，操作更加简单。不再使用内标，复杂基质的样品也能检测。

ACCESSIBILITY 辅助功能

Customer can easily access the combustion tube for daily maintenance.Cleaning and set up of tubes are more convenient.用户可以更加方便的查看裂解管，进行日常的查看，维护和拆卸清理。
NEW SOFTWARE,FULL AUTOMATIC OPERATION & SHUT DOWN 全新的软件，全自动的操作和关机
Fully automatic operation is available from calibration.boat prebake to sample analysis.
全自动操作同样适用于校准，样品分析时样品舟的预烧。
Also auto shut down is configurable by simple 3 steps,[heater off],[GA-210 wash],and [gas valve off].
同样自动关机也分为简单的三步，[加热炉关闭]，[GA-210自动清洗]，[关闭气阀]。

Measuring Principle测量原理

After samples are thermally digested in the Argon atmosphere they are combusted with oxygen and H2O.Sulfur in the samples changes to SOx and Halogens turn to Hydrogen Halide and Halogen gas.These elements will be trapped by the absorbent solution,then injected for IC analysis.
样品由Ar载气带入，加热分解后，在氧气中裂解燃烧.。样品中S转化成SOx，卤素转化成卤化氢和卤素气体。这些元素被吸收液吸收，然后注入离子色谱分析

Sample	In the combustion tube	In the absorbent
Sulfur	SOx	SO₄^2-	Ion Chromatogaph
Halogen	HX,X₂	X^-	Ion Chromatogaph

Standard Method标准方法

METHOD NUMBER	TITLE	ELEMENTS
ASTM D5987	Standard Test Method for Total Fluorine in Coal and Coke by Pyrohydrolytic Extraction and Ion Selective Electrode or Ion Chromatograph Methods	F
ASTM D7359	Standard Test Method for Total Fluorine,Chlorine and Sulfur in Aromatic Hydrocarbons and Their Mixture by Oxidative Pyrohydrolytic Combustion followed by Ion Chromatography Detection(Combustion Ion Chromatography-CIC	F,Cl,S
JIS K7392	Total bromine in waste plastics	Br
JIS R9301(ISO 2828)	Alumina powder:Determination of Fluorine content	F
JIS R1616	Methods for chemical analysis of fine silicon carbide powders for fine ceramics	F,Cl
JIS R1603	Methods for chemical analysis of fine nitride powders for fine ceramics	F,Cl
JIS Z7302	Densified refuse derived fuel-test method for total chlorine/sulfur contents	Cl,S
JEITA ET-7304A	Definition of Halogen-free Soldering Materials	F,Cl,Br,I
KS M0180	Standard Test Method for halogen(F,Cl,Br)and Sulfur content by oxidative pyrohydrolytic combustion followed by ion chromatography detection for electronic equipment	F,Cl,Br,S

MAINTENANCE维护

Open/close furnace:Easier access to the pyrolysis tube in horizontal furnace.
打开/关闭炉膛：水平炉更容易放入取出裂解管
Gas absorption unit: Easy setup by stand alone operation.
气体吸收单元：独立运行易于设置。

SAFETY FEATURE OF MONITORING 安全性检查

Gas flow:To protect from incomplete combustion, preventing irregular combustion.
气体流量：防止不完全，不规则燃烧。
Furnace:Emergency shutdown of the system in case of over heating.
电炉：过热紧急关闭系统。
Furnace door:Error message will inform open furnace door open.
电炉门：打开电炉门生成错误信息。

GAS ABSORPTION UNIT 气体吸收单元

Intuitive icon for easy setup and maintenance.Operable by single unit.[Collection] function enables the use of other analyzers,ICP,AA,etc.
直观的图标易于设置和维护。单键操作，[Collection] 键可提供吸收液给其他仪器，ICP,AA,等。

APPLICATION 应用

Electronics-Printed Circuit Board,IC's,solder,plastics,adhesives
电子工业-印刷电路板，集成电路，焊料，塑料，粘合剂
Organic synthesis- dye,pigment,organic metal,raw material of medicine,intermediates
有机合成-染料，色素，有机金属，药品原料，中间体
Automobile- rubber,plastics
汽车工业-橡胶，塑料

附件：

裂解燃烧离子色谱法测定印刷电路PCB中树脂的氟氯溴含量.pdf
裂解燃烧离子色谱法测定电子电器材料焊锡中氯溴硫的含量.pdf
裂解燃烧离子色谱法测定电子电器材料液晶屏LCD中氯碘硫的含量.pdf
裂解燃烧离子色谱法测定调色剂中氟氯硫的含量.pdf