资料Polymer analysis by GPC-SEC有兴趣的可以看看 Introduction Gel Permeation Chromatography (GPC), also referred to as Size Exclusion Chromatography (SEC) is a mode of liquid chromatography in which the components of a mixture are separated on the basis of size. In GPC-SEC large molecules elute from the column first, followed by smaller molecules. It is an important tool for the analysis of polymers. The essential results are molecular weight data and molecular weight distribution curves which are needed to characterize a polymer with regard to differences in properties. GPC-SEC is mainly used for samples with a molecular weight above 2000 although it is also in use for oligomer separations. There is no upper limit in the molecular weight, even polymer analyses with molecular weights of several millions are possible. Demands on the instrumentation are very stringent due to a special calibration procedure using a linear elution volume on the x-axis versus a logarithmic molecular weight on the y-axis. Technical Note