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【求助】能位兄弟帮忙能提供甾体类的核磁数据,小弟最近解谱棘手

  • nike168168
    2007/02/26
  • 私聊

核磁谱图交流

  • 能位兄弟帮忙能提供甾体类的核磁数据,小弟最近解谱棘手
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  • celan

    第1楼2007/02/27

    甾体骨架类型有多种,其NMR数据也比较丰富,文献很多很多.请具体点.

    nike168168 发表:能位兄弟帮忙能提供甾体类的核磁数据,小弟最近解谱棘手

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  • nike168168

    第2楼2007/03/12

    多谢楼上热心兄弟的关注,我需要的是C21甾体类的核磁数据,指点指点啊

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  • celan

    第3楼2007/03/13

    Assignment of the 1H and 13C NMR spectra of the C21 steroids 12--O-acetyltenacigenin A and tenacigenin A by two-dimensional NMR techniques and computer modeling

    Magnetic Resonance in Chemistry
    Volume 31, Issue 3 , Pages 215 - 221

    Abstract
    Stereochemical assignments of the C21 steroids 12--O-acetyltenacigenin A and tenacigenin A were performed by use of two-dimensional phase-sensitive COSY, ROESY, 1H and 13C shift correlation spectroscopy (HETCOR and FLOCK), and ambiguous assignments were resolved through molecular modeling comparisons. This combination of techniques is applicable for the assignment of the highly overlapped 1H signals of these steroids.

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  • nike168168

    第4楼2007/03/17

    谢谢楼上的兄弟,我去找了你所提供的那篇文章,但是它需要从加拿大购买,不知你有否此文章能共享一下?先谢了

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