方案摘要
方案下载应用领域 | |
检测样本 | |
检测项目 | |
参考标准 |
文献名: Adsorption of copolymers aggregates: From kinetics to adsorbed layer structure 作者: Bogdan Zdyrkoa, Pazit Bar-Yosef Ofira, Alina M. Albb, Wayne F. Reedb, Maria M. Santorea, a Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA 01003, USA b Department of Physics, Tulane University, New Orleans, LA 70118, USA 摘要:We examined the adsorption, on hydrophobic and hydrophilic surfaces, of 4 rake-type poly(dimethyl siloxane) (PDMS) copolymers varying the amount of poly(ethylene glycol) (PEG) graft arms from 41 to 72%. The copolymers formed large aggregates in solution, complicating their adsorption kinetics and layer structures. We found the adsorption process always to be dominated by the adsorption of large aggregates, with strongly bound layers resistant to rinsing in adsorbing buffer. Adsorbed amounts were nearly independent of the substrate. However, subtleties in the adsorption kinetics suggested different layer structures for the different systems. On hydrophilic silica, aggregates adsorbed at the transport limited rate until surface saturation, and associated interfacial structures were likely retained. On the hydrophobic surface, a subset of the copolymers exhibited retarded late stage adsorption kinetics suggestive of brush formation. This work demonstrates how subtle differences in adsorption kinetics provide insight into potential interfacial layer structures. 关键词:Polymer brush adsorption; Aggregate adsorption; Micelle adsorption; Associated adsorbed layer; Mushroom layer; Adsorbed copolymers; Copolymer layers; Adsorption kinetics
NanoBrook产品应用-12-ZetaPALS
NanoBrook产品应用-16-ZetaPALS
相关产品
NanoBrook 173Plus多角度粒度分析仪
布鲁克海文高灵敏Zeta电位分析仪ZetaPALS
布鲁克海文Zeta电位分析仪 ZetaPlus
布鲁克海文(Brookhaven)多角度粒度分析仪173Pl
EyeTech 激光光阻粒度粒形分析仪
布鲁克海文 多角度粒度及高灵敏Zeta电位分析仪 Omni
布鲁克海文高灵敏度Zeta电位及粒度分析仪90Plus PALS
布鲁克海文Zeta电位及激光粒度分析仪90Plus Zeta
布鲁克海文激光粒度仪90Plus
布鲁克海文广角动/静态激光散射仪BI-200SM
布鲁克海文多角度激光光散射(绝对分子量测定)仪MwA
布鲁克海文圆盘式离心/沉降粒度仪
布鲁克海文高灵敏在线粒度分析仪NanoDLS
布鲁克海文ACOS实时在线粒度检测系统
高浓度粒度分析仪
关注
拨打电话
留言咨询