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超100种PFAS！美国有毒物质释放清单更新！

蔡蔡

2024.10.18 点击0次

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导读：美国环境保护局(EPA)提议：将16种单独的PFAS和15个PFAS类别（即超过100种单独的PFAS）添加到有毒物质释放清单中，并将其指定为特别关注的化学物质。

2024年10月2日，美国环境保护局(EPA)提议：将16种单独的PFAS和15个PFAS类别（即超过100种单独的PFAS）添加到有毒物质释放清单中，并将其指定为特别关注的化学物质。

超100种PFAS！美国有毒物质释放清单更新！

16个单独PFAS物质
Chemical NameCAS No.
Broflanilide1207727-04-5
1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(2-hydroxyethyl)-N-methyl34454-97-2
1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl68298-12-4
Cyclopentene, 1,3,3,4,4,5,5-heptafluoro-1892-03-1
Ethanesulfonamide, 1,1,2,2,2-pentafluoro-N-
[(pentafluoroethyl)sulfonyl]-, lithium salt		132843-44-8
6:2 Fluorotelomer alcohol647-42-7
Fulvestrant129453-61-8
Hexaflumuron86479-06-3
Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-
(trifluoromethyl)-		132182-92-4
Perfluorotridecanoic acid72629-94-8
Perfluoro(2-ethoxy-2-fluoroethoxy)acetic acid ammonium
salt		908020-52-0
2-Propenoic acid, 2-
[methyl[(nonafluorobutyl)sulfonyl]amino]ethyl ester 		67584-55-8
Pyrifluquinazon337458-27-2
Tetraconazole112281-77-3
Triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tri-decafluorooctyl)silane51851-37-7
Trifluoro(trifluoromethyl) oxirane428-59-1
15个PFAS类别
Category Name
9-chlorohexadecafluoro-3-oxanone-1-sulfonic acid (9Cl-PF3ONS) (CASRN 756426-58-1), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
73606-19-6: potassium 9-chlorohexadecafluoro-3-oxanonane-1 sulfonate
11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3OUdS) (CASRN 763051-92-9), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
83329-89-9: potassium 11-chloroeicosafluoro-3-oxaundecane-1-sulfonate.
Hexafluoropropylene oxide dimer acid (HFPO-DA, GenX) (CASRN 13252-13-6), salts, and acyl halides (includes all associated salts and acyl halides,
including the following):
 2062-98-8: propanoyl fluoride, 2,3,3,3-tetrafluoro-2 (heptafluoropropoxy)-].
 62037-80-3: ammonium perfluoro-2-methyl-3-oxahexanoate.
 67118-55-2: potassium 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propanoate.
67963-75-1: sodium 2,3,3,3-tetrafluoro2(heptafluoropropoxy)propanoate.
Perfluorobutanesulfonic acid (PFBS), salts, sulfonyl halides, and anhydride (CASRN 375-73-5) (includes all associated salts and sulfonyl halides, including the following):
 375-72-4: perfluorobutanesulfonyl fluoride.
 29420-49-3: potassium perfluorobutane sulfonate.
 36913-91-4: perfluorobutanesulfonic anhydride.
 60453-92-1: sodium nonafluorobutane-1-sulfonate.
 68259-10-9: ammonium perfluorobutanesulfonate.
 70225-18-2: bis(2-hydroxyethyl)ammonium perfluorobutanesulfonate.
 131651-65-5: lithium nonafluorobutane-1-sulfonate.
 220689-12-3: tetrabutylphosphonium perfluorobutanesulfonate.
 507453-86-3: magnesium nonafluorobutanesulfonate.
Perfluorobutanoic acid (PFBA) (CASRN 375-22-4), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 335-42-2: perfluorobutanoyl fluoride.
 336-59-4: perfluorobutanoic anhydride.
 375-16-6: heptafluorobutyryl chloride.
 2218-54-4: sodium perfluorobutanoate.
 2966-54-3: potassium perfluorobutanoate.
 3794-64-7: silver heptafluorobutyrate.
 10495-86-0: ammonium perfluorobutanoate.
73755-28-9: rhodium(II) perfluorobutyrate dimer.
Perfluorodecanoic acid (PFDA) (CASRN 335-76-2), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 307-38-0: perfluorodecanoyl chloride.
 3108-42-7: ammonium Perfluorodecanoate.
 3830-45-3: sodium Perfluorodecanoate.
942199-24-8: perfluorodecanoic anhydride.
Perfluorododecanoic acid (PFDoA) (CASRN 307-55-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 3793-74-6: ammonium tricosafluorododecanoate.
1456735-80-0: perfluorododecanoic anhydride.
Perfluorohexanesulfonic acid (PFHxS) (CASRN 355-46-4), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides,
including the following):
 423-50-7: perfluorohexanesulfonyl fluoride.
 3871-99-6: potassium perfluorohexanesulfonate.
 55120-77-9: lithium perfluorohexanesulfonate.
 68259-08-5: ammonium perfluorohexanesulfonate.
 70225-16-0: bis(2-hydroxyethyl)ammonium perfluorohexanesulfonate.
 82382-12-5: sodium perfluorohexanesulfonate.
109065-55-6: perfluorohexanesulfonic anhydride.
Perfluorohexanoic acid (PFHxA) (CASRN 307-24-4), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 308-13-4: perfluorohexanoic anhydride.
 336-02-7: silver perfluorohexanoate.
 355-38-4: perfluorohexanoyl fluoride.
 335-53-5: perfluorohexanoyl chloride.
 2923-26-4: sodium perfluorohexanoate.
 3109-94-2: potassium undecafluorohexanoate.
21615-47-4: ammonium perfluorohexanoate
Perfluorononanoic acid (PFNA) (CASRN 375-95-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 558-95-2: heptadecafluorononanoyl fluoride.
 4149-60-4: ammonium perfluorononanoate.
 21049-38-7: potassium perfluorononanoate.
 21049-39-8: sodium heptadecafluorononanoate.
 52447-23-1: heptadecafluorononanoyl chloride.
228407-54-3: perfluorononanoic anhydride.
1H,1H, 2H, 2H-Perfluorooctane sulfonic acid (6:2 FTS) (CASRN 27619-97-2), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
 2043-57-4: 1H,1H,2H,2H-Perfluorooctyl iodide.
 27619-89-2: 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonyl
chloride.
 27619-94-9: sodium 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctane-1-sulfonate.
 59587-38-1: potassium 3,3,4,4,5,5,6,6,7,7,8,8,8-
tridecafluorooctanesulfonate.
 59587-39-2: 6:2 fluorotelomer sulfonate ammonium.
 1807944-82-6: 1-octanesulfonic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-
tridecafluoro-, barium salt (2:1).
Perfluorooctanoic acid (PFOA) (CASRN 335-67-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 335-64-8: pentadecafluorooctanoyl chloride.
 335-66-0: pentadecafluorooctanoyl fluoride.
335-93-3: silver perfluorooctanoate.
335-95-5: sodium perfluorooctanoate.
 2395-00-8: potassium perfluorooctanoate.
 3825-26-1: ammonium perfluorooctanoate.
 17125-58-5: lithium perfluorooctanoate.
 17125-60-9: cesium perfluorooctanoate.
 33496-48-9: perfluorooctanoic anhydride.
 68141-02-6: chromium perfluorooctanoate.
98065-31-7: potassium pentadecafluorooctanoate--water (1:1:2).
Perfluorooctanesulfonic acid (PFOS) (CASRN 1763-23-1), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
 307-35-7: perfluorooctylsulfonyl fluoride.
 423-92-7: perfluorooctanesulfonic anhydride.
 2795-39-3: potassium perfluorooctanesulfonate.
 4021-47-0: sodium perfluorooctanesulfonate.
 29081-56-9: ammonium perfluorooctanesulfonate.
 29457-72-5: lithium perfluorooctanesulfonate.
 56773-42-3: tetraethylammonium perfluorooctanesulfonate.
 70225-14-8: 1-octanesulfonic acid,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-
heptadecafluoro-, compd. with 2,2'-iminobis[ethanol] (1:1).
 91036-71-4: magnesium bis(heptadecafluorooctanesulfonate).
111873-33-7: tetrabutylammonium perfluorooctanesulfonate.
Perfluoropropanoic acid (PFPrA) (CASRN 422-64-0), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 356-42-3: pentafluoropropanoic anhydride.
 378-76-7: potassium perfluoropropanoate.
 378-77-8: sodium perfluoropropanoate.
 422-59-3: perfluoropropanoyl chloride.
422-61-7: perfluoropropanoyl fluoride.
Perfluoroundecanoic acid (PFUnA) (CASRN 2058-94-8), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 4234-23-5: ammonium perfluoroundecanoate.
 30377-53-8: potassium perfluoroundecanoate.
 60871-96-7: sodium perfluoroundecanoate.
 97163-17-2: calcium perfluoroundecanoate.
942199-03-3: perfluoroundecanoic anhydride.

美国有毒物质释放清单

超100种PFAS！美国有毒物质释放清单更新！

有毒物质释放清单(Toxics Release Inventory，TRI)，是美国EPA根据《应急规划和社区知情权法》(EPCRA)第313条款创建的一个数据库。

TRI旨在跟踪可能对人类健康和环境构成威胁的某些有毒化学物质的管理情况。自1986年首次实施以来，TRI已成为提供关于有毒化学物质释放与转移公共信息的重要工具。它帮助社区了解他们所在地区的潜在环境健康风险，并促进工业界采取措施减少这些化学物质的排放。目前，TRI清单共含794种单独的物质，以及33个物质类别。如果清单内物质的生产、加工或其他方式使用数量超过阈值，企业需要向EPA报告处理和排放等情况。


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2024年10月2日，美国环境保护局(EPA)提议：将16种单独的PFAS和15个PFAS类别（即超过100种单独的PFAS）添加到有毒物质释放清单中，并将其指定为特别关注的化学物质。

超100种PFAS！美国有毒物质释放清单更新！

16个单独PFAS物质
Chemical NameCAS No.
Broflanilide1207727-04-5
1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(2-hydroxyethyl)-N-methyl34454-97-2
1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl68298-12-4
Cyclopentene, 1,3,3,4,4,5,5-heptafluoro-1892-03-1
Ethanesulfonamide, 1,1,2,2,2-pentafluoro-N-
[(pentafluoroethyl)sulfonyl]-, lithium salt		132843-44-8
6:2 Fluorotelomer alcohol647-42-7
Fulvestrant129453-61-8
Hexaflumuron86479-06-3
Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-
(trifluoromethyl)-		132182-92-4
Perfluorotridecanoic acid72629-94-8
Perfluoro(2-ethoxy-2-fluoroethoxy)acetic acid ammonium
salt		908020-52-0
2-Propenoic acid, 2-
[methyl[(nonafluorobutyl)sulfonyl]amino]ethyl ester 		67584-55-8
Pyrifluquinazon337458-27-2
Tetraconazole112281-77-3
Triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tri-decafluorooctyl)silane51851-37-7
Trifluoro(trifluoromethyl) oxirane428-59-1
15个PFAS类别
Category Name
9-chlorohexadecafluoro-3-oxanone-1-sulfonic acid (9Cl-PF3ONS) (CASRN 756426-58-1), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
73606-19-6: potassium 9-chlorohexadecafluoro-3-oxanonane-1 sulfonate
11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3OUdS) (CASRN 763051-92-9), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
83329-89-9: potassium 11-chloroeicosafluoro-3-oxaundecane-1-sulfonate.
Hexafluoropropylene oxide dimer acid (HFPO-DA, GenX) (CASRN 13252-13-6), salts, and acyl halides (includes all associated salts and acyl halides,
including the following):
 2062-98-8: propanoyl fluoride, 2,3,3,3-tetrafluoro-2 (heptafluoropropoxy)-].
 62037-80-3: ammonium perfluoro-2-methyl-3-oxahexanoate.
 67118-55-2: potassium 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propanoate.
67963-75-1: sodium 2,3,3,3-tetrafluoro2(heptafluoropropoxy)propanoate.
Perfluorobutanesulfonic acid (PFBS), salts, sulfonyl halides, and anhydride (CASRN 375-73-5) (includes all associated salts and sulfonyl halides, including the following):
 375-72-4: perfluorobutanesulfonyl fluoride.
 29420-49-3: potassium perfluorobutane sulfonate.
 36913-91-4: perfluorobutanesulfonic anhydride.
 60453-92-1: sodium nonafluorobutane-1-sulfonate.
 68259-10-9: ammonium perfluorobutanesulfonate.
 70225-18-2: bis(2-hydroxyethyl)ammonium perfluorobutanesulfonate.
 131651-65-5: lithium nonafluorobutane-1-sulfonate.
 220689-12-3: tetrabutylphosphonium perfluorobutanesulfonate.
 507453-86-3: magnesium nonafluorobutanesulfonate.
Perfluorobutanoic acid (PFBA) (CASRN 375-22-4), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 335-42-2: perfluorobutanoyl fluoride.
 336-59-4: perfluorobutanoic anhydride.
 375-16-6: heptafluorobutyryl chloride.
 2218-54-4: sodium perfluorobutanoate.
 2966-54-3: potassium perfluorobutanoate.
 3794-64-7: silver heptafluorobutyrate.
 10495-86-0: ammonium perfluorobutanoate.
73755-28-9: rhodium(II) perfluorobutyrate dimer.
Perfluorodecanoic acid (PFDA) (CASRN 335-76-2), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 307-38-0: perfluorodecanoyl chloride.
 3108-42-7: ammonium Perfluorodecanoate.
 3830-45-3: sodium Perfluorodecanoate.
942199-24-8: perfluorodecanoic anhydride.
Perfluorododecanoic acid (PFDoA) (CASRN 307-55-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 3793-74-6: ammonium tricosafluorododecanoate.
1456735-80-0: perfluorododecanoic anhydride.
Perfluorohexanesulfonic acid (PFHxS) (CASRN 355-46-4), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides,
including the following):
 423-50-7: perfluorohexanesulfonyl fluoride.
 3871-99-6: potassium perfluorohexanesulfonate.
 55120-77-9: lithium perfluorohexanesulfonate.
 68259-08-5: ammonium perfluorohexanesulfonate.
 70225-16-0: bis(2-hydroxyethyl)ammonium perfluorohexanesulfonate.
 82382-12-5: sodium perfluorohexanesulfonate.
109065-55-6: perfluorohexanesulfonic anhydride.
Perfluorohexanoic acid (PFHxA) (CASRN 307-24-4), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 308-13-4: perfluorohexanoic anhydride.
 336-02-7: silver perfluorohexanoate.
 355-38-4: perfluorohexanoyl fluoride.
 335-53-5: perfluorohexanoyl chloride.
 2923-26-4: sodium perfluorohexanoate.
 3109-94-2: potassium undecafluorohexanoate.
21615-47-4: ammonium perfluorohexanoate
Perfluorononanoic acid (PFNA) (CASRN 375-95-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 558-95-2: heptadecafluorononanoyl fluoride.
 4149-60-4: ammonium perfluorononanoate.
 21049-38-7: potassium perfluorononanoate.
 21049-39-8: sodium heptadecafluorononanoate.
 52447-23-1: heptadecafluorononanoyl chloride.
228407-54-3: perfluorononanoic anhydride.
1H,1H, 2H, 2H-Perfluorooctane sulfonic acid (6:2 FTS) (CASRN 27619-97-2), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
 2043-57-4: 1H,1H,2H,2H-Perfluorooctyl iodide.
 27619-89-2: 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonyl
chloride.
 27619-94-9: sodium 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctane-1-sulfonate.
 59587-38-1: potassium 3,3,4,4,5,5,6,6,7,7,8,8,8-
tridecafluorooctanesulfonate.
 59587-39-2: 6:2 fluorotelomer sulfonate ammonium.
 1807944-82-6: 1-octanesulfonic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-
tridecafluoro-, barium salt (2:1).
Perfluorooctanoic acid (PFOA) (CASRN 335-67-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 335-64-8: pentadecafluorooctanoyl chloride.
 335-66-0: pentadecafluorooctanoyl fluoride.
335-93-3: silver perfluorooctanoate.
335-95-5: sodium perfluorooctanoate.
 2395-00-8: potassium perfluorooctanoate.
 3825-26-1: ammonium perfluorooctanoate.
 17125-58-5: lithium perfluorooctanoate.
 17125-60-9: cesium perfluorooctanoate.
 33496-48-9: perfluorooctanoic anhydride.
 68141-02-6: chromium perfluorooctanoate.
98065-31-7: potassium pentadecafluorooctanoate--water (1:1:2).
Perfluorooctanesulfonic acid (PFOS) (CASRN 1763-23-1), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following):
 307-35-7: perfluorooctylsulfonyl fluoride.
 423-92-7: perfluorooctanesulfonic anhydride.
 2795-39-3: potassium perfluorooctanesulfonate.
 4021-47-0: sodium perfluorooctanesulfonate.
 29081-56-9: ammonium perfluorooctanesulfonate.
 29457-72-5: lithium perfluorooctanesulfonate.
 56773-42-3: tetraethylammonium perfluorooctanesulfonate.
 70225-14-8: 1-octanesulfonic acid,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-
heptadecafluoro-, compd. with 2,2'-iminobis[ethanol] (1:1).
 91036-71-4: magnesium bis(heptadecafluorooctanesulfonate).
111873-33-7: tetrabutylammonium perfluorooctanesulfonate.
Perfluoropropanoic acid (PFPrA) (CASRN 422-64-0), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 356-42-3: pentafluoropropanoic anhydride.
 378-76-7: potassium perfluoropropanoate.
 378-77-8: sodium perfluoropropanoate.
 422-59-3: perfluoropropanoyl chloride.
422-61-7: perfluoropropanoyl fluoride.
Perfluoroundecanoic acid (PFUnA) (CASRN 2058-94-8), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following):
 4234-23-5: ammonium perfluoroundecanoate.
 30377-53-8: potassium perfluoroundecanoate.
 60871-96-7: sodium perfluoroundecanoate.
 97163-17-2: calcium perfluoroundecanoate.
942199-03-3: perfluoroundecanoic anhydride.

美国有毒物质释放清单

超100种PFAS！美国有毒物质释放清单更新！

有毒物质释放清单(Toxics Release Inventory，TRI)，是美国EPA根据《应急规划和社区知情权法》(EPCRA)第313条款创建的一个数据库。

TRI旨在跟踪可能对人类健康和环境构成威胁的某些有毒化学物质的管理情况。自1986年首次实施以来，TRI已成为提供关于有毒化学物质释放与转移公共信息的重要工具。它帮助社区了解他们所在地区的潜在环境健康风险，并促进工业界采取措施减少这些化学物质的排放。目前，TRI清单共含794种单独的物质，以及33个物质类别。如果清单内物质的生产、加工或其他方式使用数量超过阈值，企业需要向EPA报告处理和排放等情况。