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【资料】—残留分析中几个相关IUPAC基本概念的文献

  • 我在故我思
    2008/06/12
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  • Guidelines For Calibration In Analytical Chemistry Part 2. Multispecies Calibration (Iupac Technical Report)
    Abstract:
    Calibration in analytical chemistry refers to the relation between sample domain and measurement domain (signal domain) expressed by an analytical function x = fs(Q) representing a pattern of chemical species Q and their amounts or concentrations x in a given test sample on the one hand and a measured function y = f(z) that may be a spectrum, chromatogram, etc. Simultaneous multispecies analyses are carried out mainly by spectroscopic and chromatographic methods in a more or less selective way. For the determination of n species Qi (i = 1, 2…n), at least n signals must be measured which should be well separated in the ideal case. In analytical practice, the situation can be different.
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  • 我在故我思

    第1楼2008/06/12

    Use Of The Terms “Recovery” And “Apparent Recovery” In Analytical Procedures(Iupac Recommendations 2002)Abstract:
    The terms recovery and apparent recovery are recommended to avoid confusion caused by the use of the term recovery to cover two distinct situations. These situations deal with: (a) the yield of a preconcentration or extraction stage of an analytical process (where recovery is recommended) and (b) the quantity observed value/reference value, obtained using an analytical procedure that involves a calibration graph (where apparent recovery is recommended).

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  • 我在故我思

    第2楼2008/06/12

    Selectivity in analytical chemistry (IUPAC Recommendations 2001)
    Abstract:
    The correct use of the term “selectivity” and its clear distinction from the term “specificity” are discussed. A definition of selectivity is given, and it is recommended that the use of this term be promoted and that the use of the term “specificity” be discouraged.

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