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【求助】氯磺酸氯甲酯

  • shmily1111
    2009/11/20
  • 私聊

分析化学

  • 最近遇到一个试剂--氯磺酸氯甲酯,自己在网上找了下,相关资料很少,有高手了解的话,望能给点相关资料和检测方法。
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  • 熊猫宝宝

    第1楼2009/11/20

    英 文 名:Chloromethyl chlorosulfate
    CAS NO:49715-04-0
    分 子 式:CH2Cl2O3S
    外 观:无色透明液体,有刺激性气味
    含 量:≥95.0%
    用 途:用于生产抗生素药物舒他西林

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  • 该帖子已被版主-工农兵加3积分,加2经验;加分理由:感谢应助!
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  • 熊猫宝宝

    第2楼2009/11/20

    密度 1.631
    沸点 45-50 ºC (10 MMHG)
    折射率 1.446-1.448
    闪点 176 ºF
    水溶性 起反应

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  • 熊猫宝宝

    第3楼2009/11/20

    Product Identification Back to Contents
    【Product Name】

    Chloromethyl chlorosulfate
    【Synonyms】

    Chloro chloromethyl sulfate
    Chlorosulfuric acid, chloromethyl ester
    【CAS】

    49715-04-0
    【Formula】

    CH2Cl2O3S
    【Molecular Weight】

    164.99
    【EINECS】

    256-442-1
    【Beilstein/Gmelin】

    1703401
    【Beilstein Reference】

    3-01-00-02593
    Physical and Chemical Properties Back to Contents
    【Appearance】

    Colorless to light yellow liquid.
    【Boiling Point】

    153 - 155
    【Density】

    1.63 g/cm3
    First Aid Measures Back to Contents
    【Ingestion】

    Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
    【Inhalation】

    Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
    【Skin】

    Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
    【Eyes】

    Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
    Handling and Storage Back to Contents
    【Storage】

    Store in a tightly closed container. Keep under an argon blanket. Refrigerator (approx 4 C).
    【Handling】

    Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Container should be opened by a technically qualified person. Use only in a chemical fume hood.
    Hazards Identification Back to Contents
    【Ingestion】

    Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
    【Inhalation】

    May be fatal if inhaled. Causes chemical burns to the respiratory tract.
    【Skin】

    Causes skin burns.
    【Eyes】

    Causes eye burns.
    【Hazards】

    Contact with metals may evolve flammable hydrogen gas.
    【UN (DOT)】

    2927
    Exposure Controls/Personal Protection Back to Contents
    【Personal Protection】

    Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
    【Respirators】

    Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
    Fire Fighting Measures Back to Contents
    【Fire Fighting】

    Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
    【Fire Potential】

    Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
    Accidental Release Measures Back to Contents
    【Small spills/leaks】

    Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
    Stability and Reactivity Back to Contents
    【Stability】

    No data.
    【Incompatibilities】

    Strong oxidizing agents, alkali metals.
    【Decomposition】

    Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide.
    【Combustion Products】

    Fire may produce irritating, corrosive and/or toxic gases.
    Transport Information Back to Contents
    【UN Number】

    2927
    【Hazard Class】

    6.1
    【Packing Group】

    I; II

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  • 工农兵

    第4楼2009/11/20

    中文的话更完美了

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  • shmily1111

    第5楼2009/11/21

    虽然翻起来有点麻烦,但还是十分感谢!!!

    熊猫宝宝(cbjcn1985) 发表:Product Identification Back to Contents
    【Product Name】

    Chloromethyl chlorosulfate
    【Synonyms】

    Chloro chloromethyl sulfate
    Chlorosulfuric acid, chloromethyl ester
    【CAS】

    49715-04-0
    【Formula】

    CH2Cl2O3S
    【Molecular Weight】

    164.99
    【EINECS】

    256-442-1
    【Beilstein/Gmelin】

    1703401
    【Beilstein Reference】

    3-01-00-02593
    Physical and Chemical Properties Back to Contents
    【Appearance】

    Colorless to light yellow liquid.
    【Boiling Point】

    153 - 155
    【Density】

    1.63 g/cm3
    First Aid Measures Back to Contents
    【Ingestion】

    Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
    【Inhalation】

    Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
    【Skin】

    Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
    【Eyes】

    Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
    Handling and Storage Back to Contents
    【Storage】

    Store in a tightly closed container. Keep under an argon blanket. Refrigerator (approx 4 C).
    【Handling】

    Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Container should be opened by a technically qualified person. Use only in a chemical fume hood.
    Hazards Identification Back to Contents
    【Ingestion】

    Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
    【Inhalation】

    May be fatal if inhaled. Causes chemical burns to the respiratory tract.
    【Skin】

    Causes skin burns.
    【Eyes】

    Causes eye burns.
    【Hazards】

    Contact with metals may evolve flammable hydrogen gas.
    【UN (DOT)】

    2927
    Exposure Controls/Personal Protection Back to Contents
    【Personal Protection】

    Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
    【Respirators】

    Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
    Fire Fighting Measures Back to Contents
    【Fire Fighting】

    Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
    【Fire Potential】

    Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
    Accidental Release Measures Back to Contents
    【Small spills/leaks】

    Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
    Stability and Reactivity Back to Contents
    【Stability】

    No data.
    【Incompatibilities】

    Strong oxidizing agents, alkali metals.
    【Decomposition】

    Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide.
    【Combustion Products】

    Fire may produce irritating, corrosive and/or toxic gases.
    Transport Information Back to Contents
    【UN Number】

    2927
    【Hazard Class】

    6.1
    【Packing Group】

    I; II

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  • 儒雅凤

    第6楼2009/11/23

    氯磺酸氯甲酯,又名:氯甲基氯磺酸酯

    基本信息:
    产品名称 氯甲基氯磺酸酯
    英文名称 Chloromethyl chlorosulfate
    分子结构
    分子式 CH2Cl2O3S
    分子量 165.00
    CAS号 49715-04-0
    EINECS号 256-442-1
    物理化学性质:
    密度 1.631
    沸点 45-50 ºC (10 mmHg)
    闪点 176 ºF
    水溶性 reacts
    安全数据:
    危险品标志 说明
    危险类别码 R22;R26;R34 说明
    安全说明 S26;S28A;S36/37/39;S45 说明
    危险品运输编号 UN 1760

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