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【资料】自制染料敏化太阳能电池(图解)

电化学综合讨论

  • 有助于了解染料敏化太阳能电池的原理和制备过程.

    1.We start with 2 glass plates. Each plate is coated with TCO (or Transparent Coated Oxide). This is a thin coating which is electrically conducting in much the same way as metal wire. The TCO consists of SnO2:F (:F indicates that the tin oxide is doped with a very small amount of Fluor). The coating is transparent to enable light to pass through without loss. Doping is the process where small quantities of foreign atoms are introduced to control the electronic properties of semi conductors.

    The function of the TCO is to transport the current produced from the solar cell to the power consuming device.

    The Minus electrode goes by the name of ‘Photo electrode”


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  • leotron

    第1楼2006/08/23

    2.A thin layer of TiO2 is coated on the photo electrode. This layer consists of a spongy 3 dimensional nano crystalline network. The layer itself has a thickness of 10 micrometer and is randomly stacked. Nano technology lies at the heart of this type of solar cell. The TiO2 particles are ‘grown’ from around 3 nm to approx. 20 nm which appears to be the most optimal size for this type of dye solar cell.

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  • leotron

    第2楼2006/08/23

    3.The dye molecules attach to the TiO2 particles.

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  • leotron

    第3楼2006/08/23

    4. The plus or counter electrode is provided with a thin graphite layer. The purpose of the graphite is to act as a catalyst.

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  • leotron

    第4楼2006/08/23

    5. The electrolyte is added. The electrolyte consists of Iodine (I2) and Sodium Iodide (NaI) dissolved in ethanol.

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  • leotron

    第5楼2006/08/23

    6.The electrical circuit is completed. The solar cell kit contains both a calculator and melody module to actually show that power is being generated and used. A multimeter is included to measure resistance, voltage and current generated. The actual working of the dye solar cell is contained in a further series of slides.

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  • leotron

    第6楼2006/08/23

    7.Dye molecules chemically attach to the TiO2 particles when the negative electrode is submerged in the liquid dye.

    The transformation of photon energy into electrical current occurs in sequence as shown in the following slides:

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  • leotron

    第7楼2006/08/23

    8.A small amount of light is absorbed by the dye molecules.

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  • leotron

    第8楼2006/08/23

    9.The photon energy present is transferred to single electrons in the dye molecules.

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  • leotron

    第9楼2006/08/23

    10.Upon transfer of photon energy, the single electrons become mobile and able to leave their defined bonds.

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  • leotron

    第10楼2006/08/23

    11.The electrons have sufficient energy to migrate thru the TiO2 and TCO layers to the power consuming device.

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