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【求助】请教有关内标物的类型

  • sunrain001
    2007/12/05
  • 私聊

农残检测

  • 请教分析中内部质量控制使用的内标物是不是有所谓的程序性内标物(procedural internal standards)和仪器内标物(instrument internal standards) 不知道具体是不是这么叫的,还望高人赐教!
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  • sunrain001

    第1楼2007/12/06

    补充:上述两个词是我在翻译欧盟最新农残质量控制程序中遇到的,为方便讨论,我将整段摘录如下,另附其英文版全文:
    Acceptable limits for a individual recovery result should normally
    be in the range of the mean recovery +/- 2x %RSD and may be adjusted using repeatability (validation) and intra-laboratory reproducibility (routine on-going recovery) data. Recoveries outside this range usually require re-analysis of the batch but may be acceptable in certain justified cases. Where the individual
    recovery is unacceptably high and no residues are detected, it is not necessary to re-analyse the samples to prove the absence of residues. However, consistently high recovery should be investigated. If a significant trend occurs in recovery,
    or potentially unacceptable (beyond +/-20 %RSD) results are obtained, the cause(s) must be investigated.
    In order to assure the correct execution of the whole procedure for each individual sample and the correct injection of each final sample extract in the GC- or LC-system, the use of one or more quality control (QC-) internal standards, so-called procedurale and instrument internal standards, is recommended. These compounds, which are added to the samples prior to extraction and to the final sample extract just before injection, should be chosen to be outside of the target pesticide scope and should preferably represent the entire spectrum of pesticides in terms of polarity and susceptibility to degradation. The recovery of these QC-standards should be within the limits specified by the laboratory but at least within the abovementioned range for
    individual recovery.
    欧盟农残质量控制程序

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  • sunrain001

    第2楼2007/12/06

    另外,我对上段中提到的the mean recovery +/- 2x %RSD 及beyond +/-20 %RSD也感到很模糊,是不是什么地方印错了,是正负20 %的RSD?

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  • 我在故我思

    第3楼2007/12/06

    楼主,你好!论坛中有2002版的中文翻译,您可以参照一下: http://www.instrument.com.cn/bbs/shtml/20071010/1016372/

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  • sunrain001

    第4楼2007/12/08

    谢谢楼上版主!中文版我已下载阅读,对翻译新版很有帮助!
    只可惜并未找到此贴问题的答案,该段在02版中没有

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