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做氟谱的时候在峰的两边会有一些倒立的峰,怎样避免?

核磁共振技术(NMR)

  • 自动调相位无法消除,手动调节相位也很难达到满意的效果,在扫谱的时候怎么样可以避免这种倒立的峰的出现?
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  • 第1楼2005/03/07

    怎么和我出现的问题一样呀,有待高人指点

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  • 第2楼2005/03/16

    First of all, I don't know if your sample is solid or liquid.
    The first possible reason is the T1 relaxation times among those peaks are different and the delay time (the time between each pulse sequence) you set is not long enough, try a longer delay time (in Varian machine, it's the "d1" parameter).
    The second possible reason is that when the pulse goes into different regions in a solid sample, the phase of the pulse probably changed a bit, leading to different phases of the signals.
    Another thing you can try is to type "lp=0 rp=0" and then "wft" to see if it works.

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