仪器信息网APP

选仪器、听讲座、看资讯

立即体验

当前位置：仪器社区 >食品检测 > 农残检测 > 帖子详情

水果蔬菜中69种农药及代谢物残留量的测定

阿尔塔

2018/08/22

私聊

农残检测

3.1 提取盐包：（参考资料链接：QUICLEAR 前处理产品）

产品号	产品名称	Product Name
1ST27460-100A	乙腈中53种农药混标, 100ppm	53 Pesticides Mix Solution,100ppm
1ST27461-100B	丙酮中20种农药混标, 100ppm	20 Pesticides Mix Solution，100ppm

（参考资料链接：QUICLEAR多功能针式过滤器使用方法视频 QUICLEAR 多功能针式过滤器）

（参考资料链接：QUICLEAR平行研磨仪操作视频 QUICLEAR平行研磨仪）

序号	产品号	中文名	英文名	CAS号	RT	母离子	子离子	DP	CE
1	1ST20259	3-羟基克百威	3-Hydroxycarbofuran	16655-82-6	2.59	238	181	65	14
					2.59	238	163	65	20
2	1ST25000	阿维菌素	Avermectin B1a	71751-41-2	6.2	895.4	751.3	120	60
					6.2	895.4	449.2	120	60
3	1ST21189	苯醚甲环唑	Difenoconazole	119446-68-3	4.92	406.1	251	120	37
					4.92	406.1	337	120	23
4	1ST20298	吡虫啉	Imidacloprid	138261-41-3	2.42	256.1	209	60	23
					2.42	256.1	175	60	26
5	1ST20155	丙溴磷	Profenofos	41198-08-7	5.25	373	302.9	80	25
					5.25	373	345.2	80	18
6	1ST20345	除虫脲	Diflubenzuron	35367-38-5	4.47	311	141.2	72	47
					4.47	311	158	72	21
7	1ST25016	哒螨灵	Pyridaben	96489-71-3	6.06	365	309	110	17
					6.06	365	147	110	31
8	1ST20097	敌敌畏	Dichlorvos	62-73-7	3.31	221	109	70	23
					3.31	221	127	70	25
9	1ST20297	啶虫脒	Acetamiprid	135410-20-7	2.64	223	126	70	27
					2.64	223	99	70	47
10	1ST20001	毒死蜱	Chlorpyrifos	2921-88-2	5.62	350	198	82	29
					5.62	350	97	82	49
11	1ST20434	对硫磷	Parathion	56-38-2	4.57	292	236	80	20
					4.57	292	264	80	15
12	1ST21058	多菌灵	Carbendazim	10605-21-7	2.95	192	160	80	25
					2.95	192	132	80	41
13	1ST22249	二甲戊灵	Pendimethalin	40487-42-1	5.68	282.1	212	45	15
					5.68	282.1	194	45	25
14	1ST20094	二嗪磷	Diazinon	333-41-5	4.77	305	169	80	27
					4.77	305	153	80	28
15	1ST20094	伏杀硫磷	Phosalone	2310-17-0	4.82	368	182	71	20
					4.82	368	322	71	13
16	1ST20225	氟胺氰菊酯	Tau-fluvalinate	102851-06-9	5.97	503	181	82	25
					5.97	503	208	75	15
17	1ST20305	氟虫腈	Fipronil	120068-37-3	4.36	454	436.9	50	15
					4.36	454	367.9	50	31
18	1ST20308	氟虫腈砜	Fipronil-Sulfone	120068-36-2	4.4	421	317	82	45
					4.4	421	264.9	69	50
19	1ST20306	氟虫腈硫醚（亚砜）	Fipronil-sulfide	120067-83-6	4.5	470.1	452.9	55	35
					4.5	470.1	320	40	45
20	1ST20348	氟啶脲	Chlorfluazuron	71422-67-8	5.73	540	383	80	27
					5.73	540	158	80	24
21	1ST20502	氟甲腈	Fipronil-desulfinyl	205650-65-3	4.27	389.1	369	65	42
					4.27	389.1	213	69	48
22	1ST25001	甲氨基阿维菌素苯甲酸盐	Emamectin Benzoate	155569-91-8	5.49	886.5	158.1	120	37
					5.49	886.5	302.1	120	39
23	1ST20093	甲胺磷	Methamidophos	10265-92-6	1.58	142	94	54	19
					1.58	142	125	54	18
					1.03	142.1	94	54	19
					1.03	142.1	125	54	18
24	1ST20124	甲拌磷	Phorate	298-02-2	4.94	261.1	75.2	34	14
					4.94	261.1	199	34	11
25	1ST20123	甲拌磷砜	Phorate sulfone	2588-04-7	3.71	293	171	55	15
					3.71	293	143	55	25
26	1ST21259	甲拌磷亚砜	Phorate sulfoxide	2588-03-6	3.61	277	143	55	30
					3.61	277	199	40	15
27	1ST20140	甲基对硫磷	Parathion-methyl	298-00-0	4	264	231.9	65	23
					4	264	124.9	65	23
28	1ST20127	甲基异柳磷	Isofenphos-methyl	99675-03-3	4.53	273	231	39	13
					4.53	273	121.1	39	33
29	1ST20277	甲萘威	Carbaryl	63-25-2	3.55	202.1	145	54	15
					3.55	202.1	127	54	40
30	1ST20222	甲氰菊酯	Fenpropathrin	39515-41-8	5.68	350.2	125.1	75	30
					5.68	350.2	97.1	82	40
31	1ST20271	克百威	Carbofuran	1563-66-2	3.4	222.1	165	70	17
					3.4	222.1	123.1	70	29
32	1ST20098	乐果	Dimethoate	60-51-5	2.68	230	125	56	29
					2.68	230	199	56	13
33	1ST20210	联苯菊酯	Bifenthrin	82657-04-3	6.57	440.3	181.1	69	15
					6.57	440.3	166.2	40	50
34	1ST20168	马拉硫磷	Malathion	121-75-5	4.17	331	127	64	17
					4.17	331	285	64	13
35	1ST21247	咪鲜胺	Prochloraz	67747-09-5	4.81	376.2	308	65	17
					4.81	376.2	70.1	65	43
36	1ST21157	嘧菌酯	Azoxystrobin	131860-33-8	3.93	404.1	372	70	20
					3.93	404.1	344.1	70	34
37	1ST21161	嘧霉胺	Pyrimethanil	53112-28-0	4.17	200	107	91	34
					4.17	200	82	91	37
38	1ST20449	灭多威	Methomyl	16752-77-5	2.13	163	106	38	13
					2.13	163	88	38	13
39	1ST20349	灭幼脲	Chlorbenzuron	57160-47-1	4.62	309	156	75	20
					4.62	309	139	75	44
40	1ST20350	噻虫嗪	Thiamethoxam	153719-23-4	2.16	292	211	60	18
					2.16	292	181	60	32
41	1ST20438	三唑磷	Triazophos	24017-47-8	4.23	314	162	70	25
					4.23	314	119.1	70	47
42	1ST21202	三唑酮	Triadimefon	43121-43-3	4.21	294	197	81	21
					4.21	294	225	81	17
43	1ST20111	杀螟硫磷	Fenitrothion	122-14-5	4.25	278	125	52	25
					4.25	278	246	52	22
44	1ST20173	水胺硫磷	Isocarbophos	24353-61-5	3.8	273.1	231	67	15
					3.8	273.1	121	67	32
45	1ST20375	涕灭威	Aldicarb	116-06-3	3.18	116.1	89	47	10
					3.18	116.1	70	47	10
46	1ST20266	涕灭威砜	Aldicarb Sulfone	1646-88-4	2.05	223	148	63	12
					2.05	223	76.1	63	10
47	1ST20273	涕灭威亚砜	Aldicarb-sulfoxid	1646-87-3	1.92	207	132	51	10
					1.92	207	89	51	20
48	1ST21145	烯酰吗啉	Dimethomorph	110488-70-5	4.05	388.1	301	115	29
					4.05	388.1	165	115	43
49	1ST20170	辛硫磷	Phoxim	14816-18-3	4.74	299.1	77	67	46
					4.74	299.1	129	67	16
50	1ST20189	亚胺硫磷	Phosmet	732-11-6	3.95	318	160	55	35
					3.95	318	133	47	45
51	1ST20167	氧乐果	Omethoate	1113-02-6	1.84	214	182.9	56	16
					1.84	214	109	56	36
52	1ST20144	乙酰甲胺磷	Acephate	30560-19-1	1.03	184.1	143	50	10
					1.03	184.1	125	50	26
53	1ST21164	异菌脲	Iprodione	36734-19-7	4.49	330.1	245	55	20
					4.49	330.1	288	47	20

序号	产品号	中文名	英文名	CAS号	RT	母离子	子离子	CE
1	1ST20259	3-羟基克百威	3-Hydroxycarbofuran	16655-82-6	2.823	238.1	220	5
					2.823	238.1	181.1	5
2	1ST25000	阿维菌素	Avermectin B1a	71751-41-2	5.748	890.5	567.2	8
					5.748	890.5	305.2	12
					5.748	890.5	145.1	24
3	1ST21189	苯醚甲环唑	Difenoconazole	119446-68-3	4.503	406.1	337	15
					4.503	406.1	251	28
4	1ST20298	吡虫啉	Imidacloprid	138261-41-3	2.664	256	209	10
					2.664	256	175	10
5	1ST20155	丙溴磷	Profenofos	41198-08-7	4.772	372.9	344.9	17
					4.772	372.9	302.8	9
6	1ST20345	除虫脲	Diflubenzuron	35367-38-5	4.22	311	158	10
					4.22	311	141	15
7	1ST25016	哒螨灵	Pyridaben	96489-71-3	5.581	365.1	309	10
					5.581	365.1	146.9	20
8	1ST20097	敌敌畏	Dichlorvos	62-73-7	3.43	220.9	145	15
				3.43	220.9	109	15
9	1ST20297	啶虫脒	Acetamiprid	135410-20-7	2.834	223	126	15
					2.834	223	56	15
10	1ST20001	毒死蜱	Chlorpyrifos	2921-88-2	5.104	349.9	199.9	17
					5.104	349.9	97	17
11	1ST20434	对硫磷	Parathion	56-38-2	4.287	292	264	8
					4.287	292	235.9	10
12	1ST21058	多菌灵	Carbendazim	10605-21-7	3.128	192.1	160	12
					3.128	192.1	132	33
13	1ST22249	二甲戊灵	Pendimethalin	40487-42-1	5.184	282.1	212.1	5
					5.184	282.1	194	5
14	1ST20094	二嗪磷	Diazinon	333-41-5	4.419	305.1	169	20
					4.419	305.1	153.1	20
15	1ST20172	伏杀硫磷	Phosalone	2310-17-0	4.445	367.9	322	5
					4.445	367.9	182	10
16	1ST20225	氟胺氰菊酯	Tau-fluvalinate	102851-06-9	5.466	503.1	208	7
					5.466	503.1	181	29
17	1ST20305	氟虫腈	Fipronil	120068-37-3	6.08	435	330	-20
					6.08	435	250	-20
18	1ST20308	氟虫腈砜	Fipronil-Sulfone	120068-36-2	5.953	451	415	-15
					5.953	451	282	-30
19	1ST20306	氟虫腈硫化物	Fipronil-sulfide	120067-83-6	4.603	419	383	-10
					4.603	419	262	-30
20	1ST20502	氟甲腈	Fipronil-desulfinyl	205650-65-3	4.447	387	351	-10
					4.447	387	282	-35
21	1ST20348	氟啶脲	Chlorfluazuron	71422-67-8	5.169	539.9	382.9	19
					5.169	539.9	158	19
22	1ST25001	甲氨基阿维菌素苯甲酸盐	Emamectin Benzoate	155569-91-8	4.896	886.38	158	36
					4.896	886.38	82.7	48
23	1ST20093	甲胺磷	Methamidophos	10265-92-6	1.014	142	124.9	10
					1.014	142	94	11
24	1ST20124	甲拌磷	Phorate	298-02-2	4.552	261	199	5
					4.552	261	75	10
25	1ST20123	甲拌磷砜	Phorate sulfone	2588-04-7	3.705	293	171	5
					3.705	293	143	15
26	1ST21259	甲拌磷亚砜	Phorate sulfoxide	2588-03-6	3.667	277	199	5
					3.667	277	143	15
27	1ST20140	甲基对硫磷	Parathion-methyl	298-00-0	3.963	264	232	13
					3.963	264	125	20
28	1ST20127	甲基异柳磷	Isofenphos-methyl	99675-03-3	4.284	332.4	273.2	20
					4.284	332.4	231.2	20
29	1ST20277	甲萘威	Carbaryl	63-25-2	3.556	202.1	145	8
					3.556	202.1	117.1	18
30	1ST20222	甲氰菊酯	Fenpropathrin	39515-41-8	5.146	350.2	125.1	5
					5.146	350.2	97.1	20
31	1ST20271	克百威	Carbofuran	1563-66-2	3.463	222.1	165.1	10
					3.463	222.1	123	15
32	1ST20098	乐果	Dimethoate	60-51-5	2.892	230	198.9	5
					2.892	230	170.97	10
33	1ST20210	联苯菊酯	Bifenthrin	82657-04-3	6.179	440.1	181	12
					6.179	440.1	166	28
34	1ST20168	马拉硫磷	Malathion	121-75-5	4.032	331	126.9	5
					4.032	331	98.9	10
35	1ST21247	咪鲜胺	Prochloraz	67747-09-5	4.463	376	308	10
					4.463	376	265.9	14
36	1ST21157	嘧菌酯	Azoxystrobin	131860-33-8	3.844	404.1	372.1	6
					3.844	404.1	344.1	2
37	1ST21161	嘧霉胺	Pyrimethanil	53112-28-0	4.079	200.1	183	25
					4.079	200.1	107	25
38	1ST20449	灭多威	Methomyl	16752-77-5	2.385	163	106	8
					2.385	163	88	8
39	1ST20349	灭幼脲	Chlorbenzuron	57160-47-1	4.32	309	156	20
				4.32	309	139	20
40	1ST20350	噻虫嗪	Thiamethoxam	153719-23-4	2.425	292.03	211.04	10
				2.425	292.03	181.03	20
41	1ST20438	三唑磷	Triazophos	24017-47-8	4.082	314.1	162.1	20
					4.082	314.1	119	30
					4.082	314.1	286	10
42	1ST21202	三唑酮	Triadimefon	43121-43-3	4.066	294.1	197	15
					4.066	294.1	69	20
43	1ST20111	杀螟硫磷	Fenitrothion	122-14-5	3.664	278.1	246	15
					3.664	278.1	125	20
44	1ST20173	水胺硫磷	Isocarbophos	24353-61-5	3.752	312.3	270.2	20
					3.752	312.3	236.2	20
45	1ST20375	涕灭威	Aldicarb	116-06-3	3.243	191.08	116.05	5
					3.243	191.08	89.03	12
46	1ST20266	涕灭威砜	Aldicarb Sulfone	1646-88-4	2.2	223.07	148.04	5
					2.2	223.07	76.04	5
47	1ST20273	涕灭威亚砜	Aldicarb-sulfoxid	1646-87-3	1.029	207.08	132.05	0
					1.029	207.08	89.03	12
48	1ST21145	烯酰吗啉	Dimethomorph	110488-70-5	4.017	388.13	301.06	20
					4.017	388.13	165.01	33
49	1ST20170	辛硫磷	Phoxim	14816-18-3	4.391	299.06	129.04	9
					4.391	299.06	77.04	40
50	1ST20189	亚胺硫磷	Phosmet	732-11-6	3.889	318	160.04	5
					3.889	318	133.03	5
51	1ST20167	氧乐果	Omethoate	1113-02-6	1.03	214.03	183	8
					1.03	214.03	124.98	24
52	1ST20144	乙酰甲胺磷	Acephate	30560-19-1	1.027	184.02	142.99	4
					1.027	184.02	94.97	24
53	1ST21164	异菌脲	Iprodione	36734-19-7	4.241	330.4	288	10
					4.241	330.4	250	8

序号	产品号	中文名	英文名	CAS号	RT	分段时间	定量离子	定性离子
1	1ST20020	α-六六六	α-HCH	319-84-6	6.244	3.0-6.8	219	183,221,254
2	1ST20021	β-六六六	β-HCH	319-85-7	6.563		219	217,181,254
3	1ST20022	γ-六六六	γ-HCH	58-89-9	6.667		181	219,254,217
4	1ST20048	五氯硝基苯	Quintozene	82-68-8	6.727		295	237,249
5	1ST20023	δ-六六六	δ-HCH	319-86-8	6.981	6.8-8.0	219	217,181,254
6	1ST21120	百菌清	Chlorothalonil	1897-45-6	7.046		264	266,268
7	1ST21091	乙烯菌核利	Vinclozolin	50471-44-8	7.534		285	212,198
8	1ST20502	氟甲腈	Fipronil-desulfinyl		7.61		332	387.5,177.5
9	1ST25044	三氯杀螨醇	Dicofol	115-32-2	8.512	8.0-12.5	139	141,250,251
10	1ST20306	氟虫腈硫化物	Fipronil sulfide	120067-83-6	9.064		255	350.3,419.6
11	1ST20502	氟虫腈	Fipronil	120068-37-3	9.236		367	369,351
12	1ST21226	腐霉利	Procymidone	32809-16-8	9.483		283	285,255
13	1ST20308	氟虫腈砜	Fipronil-Sulfone	120068-36-2	10.707		212	382.3,334.2
14	1ST20396	虫螨腈	Chlorfenapyr	122453-73-0	11.133		247	328,408
15	1ST20233	高效氯氟氰菊酯	Cyhalothrin	68085-85-8	14.784, 15.007	12.5-23.6	181	197,141
16	1ST20203	氟氯氰菊酯	Cyfluthrin	68359-37-5	16.412, 16.501, 16.584, 16.619		206	199,226
17	1ST20211	氯氰菊酯	Cypermethrin	52315-07-8	16.747, 16.84, 16.939, 16.951		181	209,163,152,181
18	1ST20232	氟氰戊菊酯	Flucythrinate	70124-77-5	16.937, 17.121		199	157,451
19	1ST20202	S-氰戊菊酯	Esfenvalerate	66230-04-4	17.621, 17.808		167	225,419,181
20	1ST20223	溴氰菊酯	Deltamethrin	52918-63-5	18.294		181	172,174

序号	产品号	中文名	英文名	CAS号	RT	分段时间	母离子	子离子	CE	母离子	子离子	CE
1	1ST20020	α-六六六	α-HCH	319-84-6	6.244	3.0-6.8	218.9	183	5	216.9	181	5
2	1ST20021	β-六六六	β-HCH	319-85-7	6.563		181	145	15	216.9	181	5
3	1ST20022	γ-六六六	γ-HCH	58-89-9	6.667		182.8	146.9	15	182.8	108.9	25
4	1ST20048	五氯硝基苯	Quintozene	82-68-8	6.727		295	237	20	236.9	142.9	30
5	1ST20023	δ-六六六	δ-HCH	319-86-8	6.981	6.8-8.0	217	181.1	5	181.1	145.1	15
6	1ST21120	百菌清	Chlorothalonil	1897-45-6	7.046		266	133	35	266	170	35
7	1ST21091	乙烯菌核利	Vinclozolin	50471-44-8	7.534		187	124	20	197.9	145	15
8	1ST20502	氟甲腈	Fipronil-desulfinyl		7.61		281.1	157.1	30	281.1	204.1	10
9	1ST25044	三氯杀螨醇	Dicofol	115-32-2	8.512	8.0-12.5	139	111	15	250.9	138.9	15
10	1ST20306	氟虫腈硫醚	Fipronil-sulfide		9.064		254.9	156.9	40	212.9	142.9	35
11	1ST20502	氟虫腈	Fipronil	120068-37-3	9.236		367	213.1	30	368.8	215.1	20
12	1ST21226	腐霉利	Procymidone	32809-16-8	9.483		96	67.1	10	96	53.1	15
13	1ST20308	氟虫腈砜	Fipronil-Sulfone	120068-36-2	10.707		383	335	10	383	255	25
14	1ST20396	虫螨腈	Chlorfenapyr	122453-73-0	11.133		328	247	25	363	247	30
15	1ST20233	高效氯氟氰菊酯	Cyhalothrin	68085-85-8	14.784, 15.007	12.5-23.6	197	141	15	197	161	20
16	1ST20203	氟氯氰菊酯	Cyfluthrin	68359-37-5	16.412, 16.501, 16.584, 16.619		162.9	127	5	198.9	170.1	25
17	1ST20211	氯氰菊酯	Cypermethrin	52315-07-8	16.747, 16.84, 16.939, 16.951		163.1	91	35	163.1	127.1	5
18	1ST20232	氟氰戊菊酯	Flucythrinate	70124-77-5	16.937, 17.121		156.9	107.1	15	198.9	157	10
19	1ST20202	S-氰戊菊酯	Esfenvalerate	66230-04-4	17.621, 17.808		167	125.1	10	224.9	119	20
20	1ST20223	溴氰菊酯	Deltamethrin	52918-63-5	18.294		252.9	93	20	250.7	172	10

分
该帖子已被版主-zyl3367898加10积分，加2经验;加分理由:原创有奖