【求助】加急！六方晶系的问题

可参考以下网址:
http://www.ezkaoyan.com/school/fzu/Column7/2006-6-20/20066202722515.htm

以下转自http://en.wikipedia.org/wiki/Miller_index

With hexagonal and rhombohedral crystal systems, it is possible to use the Bravais-Miller index which has 4 numbers (h k i l)
i = −h − k.
Here h, k and l are identical to the Miller index, and i is a redundant index.
This four-index scheme for labeling planes in a hexagonal lattice makes permutation symmetries apparent. For example, the similarity between and is more obvious when the redundant index is shown.



In the figure at above, the (001) plane has a 3-fold symmetry: it remains unchanged by a rotation of 1/3 (2π/3 rad, 120°). The [100], [010] and the directions are really similar. If S is the intercept of the plane with the axis, then
i = 1/S.
There are also ad hoc schemes (e.g. in the transmission electron microscopy literature) for indexing hexagonal lattice vectors (rather than reciprocal lattice vectors or planes) with four indices. However they don't operate by similarly adding a redundant index to the regular three-index set.

For example, the reciprocal lattice vector (hkl) as suggested above can be written as ha*+kb*+lc* if the reciprocal-lattice basis-vectors are a*, b*, and c*. For hexagonal crystals this may be expressed in terms of direct-lattice basis-vectors a, b and c as

Hence zone indices of the direction perpendicular to plane (hkl) are, in suitably-normalized triplet form, simply [2h+k,h+2k,l(3/2)(a/c)^2]. When four indices are used for the zone normal to plane (hkl), however, the literature often uses [h,k,-h-k,l(3/2)(a/c)^2] instead. Thus as you can see, four-index zone indices in square or angle brackets sometimes mix a single direct-lattice index on the right with reciprocal-lattice indices (normally in round or curly brackets) on the left.

看这个对你有用不!
晶体学基础

也就是说我必须知道a和c的值才能通过那个公式推算出晶向吗？？关键是我的物象在XRD中没有确定的PDF卡对应，我无法得知确定的a/c的值啊