【求助】再请教几个问题！谢谢

想求助什么?说具体点.再讲一下背景.

再麻烦您给翻译一下
这好像是讲价带的关系，但是我不太明白！
谢谢

（1）the determining factor for the Ag cation stability in low co-ordination environments is the energetic separation between metal d orbitals and ligand p orbitals and the resulting Md–Lp interactions.
银阳离子在低配位环境中稳定性的决定性因素是金属d轨道和配体p轨道之间的能量差，以及由此导致的金属d轨道－配体p轨道相互作用。
（2）For some authors, the low degree of co-ordination is tightly linked to what is described as hybridisation or mixing between full d orbitals and empty s ones of metal. This phenomenon is related to a weak energetic separation between d and s orbitals. This interpretation, based on a d/s hybridisation, has been evoked for a long time35 and classical works36
refer to it. The importance of that factor is also reported in more recent works.
对一些作者而言，低的配位程度与所谓全满d轨道和金属空s轨道之间的混杂或混合紧密联系。这种现象与d和s轨道之间低的能量差有关。这种基于d/s混杂理论的解释在很久以前就已经被提出并且有很多经典的著作可供参考。这一因素的重要性在最近的著作中亦有报道。

不知道以上翻译是否和楼主的理解相符？不过建议下次楼主能先讲讲自己的理解，然后再让大家帮你出谋划策，这样才叫讨论嘛！

hybridisation 译成杂化我觉得比较妥帖，仅供参考，

有道理，因为我对量子化学接触的不多，所以有些词也理解不深，只是看表面意思。

谦虚了，

兄弟你是什么专业的?