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能谱定量分析的结果里,K表示什么?

  • threedaysin
    2005/11/30
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扫描电镜(SEM/EDS)

  • 最后一列的数据表示的是K值
    K表示?
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  • 第1楼2005/11/30

    这个初级问题我来回答:K、L、M、N、O是原子中电子所处的壳层 ,K是最里层。基础知识!!

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  • 第2楼2005/11/30

    K是K Factor,好像是将X射线强度转换成重量百分比或物质的量百分比的一个参数。

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  • 第3楼2005/11/30

    Ratio Standard

    A proportionality factor, known as the k factor is used to relate the characteristic X-ray intensities IA/IB in a thin sample to the actual concentrations in wt% in the form

    CA/CB = KAB.IA/IB

    where I = Intensity, and C = concentration.

    K factors

    The k-factor relates the intensity of two elements. Where more than two elements are to be analyzed, if all ratios are taken with respect to a single element (this is called the ratio standard element), these values can be regarded as elemental sensitivity factors, more usually known as k-factors.

    The theoretical k factor value is determined using the X-ray line type (K series, L series, etc) for the ratio standard you select. For a given X-ray line, A, and ratio standard line, R, the k factor kAR is calculated as follows:

    kAR = AA wR QB aR eR / AR wA QA aA eA

    where A = atomic weight; w = fluorescent yield; Q = ionisation cross section; a = the fraction of the total line, e.g. Ka / (Ka +Kb ) for a Ka line, and e = the absorption due to the detector window at that line energy.

    Once k factors are known relative to the ratio standard, any other k factors can be calculated using the formula

    kAB = kAR / kBR

    You can use any element if you are using theoretically derived k factors. Conventionally, Si is used.

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  • 第4楼2005/12/01

    也就是说是一个比较专业的参数,因子之类的吧
    哈哈,被我蒙对了,客户问我代表啥意思,俺就瞎掰说,是一个因子,你们知道了也没用的

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  • 第6楼2006/01/12

    K代表一个比例因子,是经过ZAF修正后得到的,以前手工定量计算时,K因子非常重要,但现在计算机发展了,可以直接得到定量结果,K因子对用户就不重要了

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  • liyasi

    第7楼2012/12/13

    前面的百分比都分别代表什么啊?求解释,要用到能谱,菜鸟不懂分析

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  • amdk7

    第8楼2012/12/14

    一般第一列是质量百分比,第二列是原子百分比,至于是用质量或原子百分比,就看用户自己了!

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  • amdk7

    第9楼2012/12/14

    mass% 质量百分比
    at% 原子百分比

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