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未知物定性求助

  • everlastingz
    2013/03/27
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气质联用(GCMS)

  • 悬赏金额:30积分状态:已解决
  •   12.848

      13.616

      13.863

      13.914

      14.012

      14.063 

      17.773 这几个峰不知是什么,大家帮助确定一下。另外请大家看下这个样板可能含有什么天热油类呢

symmacros 2013/03/27

12.848 Sabinene hydrate   13.616 Sabinol   13.863 alpha-dihydro-terpineol

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  • symmacros

    第1楼2013/03/27

    应助达人

    12.848 Sabinene hydrate

      13.616 Sabinol

      13.863 alpha-dihydro-terpineol

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  • symmacros

    第2楼2013/03/27

    应助达人

    14.012 camphene hydrate 

      17.773 thymol methyl ether

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  • everlastingz

    第3楼2013/03/27

    感谢朱老师22.708 是 Longipinene 吗 这个含量比较大 可能是来自于什么精油呢

    symmacros(jimzhu) 发表:14.012 camphene hydrate 

      17.773 thymol methyl ether

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  • symmacros

    第4楼2013/03/27

    应助达人

    是这个化合物。在一些Pine oil里有。例如

    Title

    Analysis of the essential oils of pine cones Pinus koraiensis Steb. Et Zucc. and P. sylvestris L. from China.

    AbstractThe chemical composition of the essential oil obtained from pine cones of Pinus koraiensis and Pinus sylvestris from northeast China was analyzed by gas chromatography (GC) and gas chromatography/mass spectrometry (Gel MS), and 35 and 31 components were identified, respectively. alpha-pinene (35.2%), limonene (18.4%), beta-pinene (8.7%), beta-caryophyllene (3.5%) and myrcene (3.0%) were the main components in P. koraiensis cone oil. Aromadendrene (20.2%), alpha-pinene (18.5%), alpha-longipinene (10.5%) and alpha-terpineol (5.5%) were the main components in P. sylvestris cone oil. The antioxidant activity of the oils from P. koraiensis and P. sylvestris was evaluated using the DPPH.


    everlastingz(everlastingz) 发表:感谢朱老师22.708 是 Longipinene 吗 这个含量比较大 可能是来自于什么精油呢

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  • everlastingz

    第5楼2013/03/27

    朱老师 13.914和14.063 这两个是什么呢

    symmacros(jimzhu) 发表:14.012 camphene hydrate 

      17.773 thymol methyl ether

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  • symmacros

    第6楼2013/03/27

    应助达人

    13.914 4Z-Verbenol, 14.063好像不是单一的峰,可能来自什么精油,不好确切推测判断。

    everlastingz(everlastingz) 发表:朱老师 13.914和14.063 这两个是什么呢

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  • everlastingz

    第7楼2013/03/27

    十分感谢朱老师的帮助

    symmacros(jimzhu) 发表:13.914 4Z-Verbenol, 14.063好像不是单一的峰,可能来自什么精油,不好确切推测判断。

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  • everlastingz

    第8楼2013/03/27

    朱老师这两个是可能来自于什么精油呢

    symmacros(jimzhu) 发表:14.012 camphene hydrate

      17.773 thymol methyl ether

0
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  • symmacros

    第9楼2013/03/27

    应助达人

    camphene hydrate具体是哪个油不知道。参考:

    The chemical constituents of the essential oil from the leaf of C. longepaniculatum were analyzed by the capillary gas chromatography. 26 Compounds have been identified by GLC & gc-MS/DS. These compounds were alpha-thujene, alpha-pinene, camphene, sabinene, beta-pinene, myrcene, alpha-phellandrene, alpha-terpinene, p-cymene, 1,8-cineole, delta-3-carene, beta-terpinene, 1,4-cineole, camphor, alpha-terpinolene, camphene hydrate, myrcenol, terpinen-4-ol, 1-alpha-terpineol, cis-piperitol, nerol, delta-elemene, humulene, cis-caryophyllene, gamma-elemene & iso-longifolene.

    thymol methyl ether在许多精油里面有,

    1 Essential oils of hairy roots and plant roots of Arnica montana L. were obtained by hydrodistillation with the yield of 0.60% and 0.40% of dry weight, respectively. Their constituents were identification using gc, gc/MS, (1)H- and (13)C-NMR. Fifty-six compounds were identified in both essential oils that consisted mainly of bifunctional thymol derivatives and sesquiterpene hydrocarbons. 10-Isobutyryloxy-8,9-didehydro-thymol isobutyrate and 10-isobutyryloxy-8,9-didehydro thymol methyl ether were the main components of both essential oils.

    2 As a part of an investigation of natural antioxidants from Dalmatian aromatic plants in this paper the authors report a study of the antioxidant activity related to the chemical composition of savory free volatile compounds. Twenty one compounds were identified m the essential oil without fractionation representing 97.4% of the total oil. The major compound was phenolic monoterpene thymol (45.2%) Other important compounds were monoterpenic hydrocarbons p-cymene (6.4%) and gamma terpinene (5.9%) and oxygen containing compounds carvacrol methyl ether (5.8%) thymol methyl ether (5.1%) carvacrol (5.3%) geraniol (5.0%) and borneol (3.9%) The evaluation of antioxidant power was performed in vitro by the beta-carotene bleaching and thiobarbituric acid (TBA) methods As determined with both methods the total savory essential oil as well as different fractions or pure constituents containing hydroxyl group exhibited relatively strong antioxidant effect. The hydrocarbons when isolated as CH fraction showed the poorest effectiveness in spite the fact that this fraction contained gamma-terpinene, alpha- terpinene, p-cymene and terpinolene which previously were identified as potential antioxidants.

    3 The essential oils of leaves and fine stems of five specimens of Lippia grandis collected at different places in the Amazon were analysed by gc-MS. These oils presented two distint(sic) chemical profiles. The percentage of the main identified compounds varied with the plant part, season time and collection site: thymol (19.3-69.7%), 1,8-cineole (22.2-56.0%), carvacrol (0.2-21.2%), (E)-nerolidol (0.8-21.1%), alpha-pinene (0.1-17.4%), p-cymene (4.0-14.0%), thymol methyl ether (1.0-14.0%) and beta-caryophyllene (0.7-12.1%). Based on the results, the authors believe to have at least two chemical varieties for Lippia grandis in the Amazon: The thymol and 1,8-cineole types.

    everlastingz(everlastingz) 发表:朱老师这两个是可能来自于什么精油呢

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  • everlastingz

    第10楼2013/03/28

    12.848 Sabinene hydrate

      13.616 Sabinol
    朱老师这两个有可能来自什么精油呢

    symmacros(jimzhu) 发表:12.848 Sabinene hydrate

      13.616 Sabinol

      13.863 alpha-dihydro-terpineol

0
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