【求助】求助：气质联用资料！谢谢！

应助达人

黑体辐射了解的人很少，像黑体辐射解离(BIRD)和PQD裂解技术也很少。

下面是应用的参考文献的简介：
文献标题：Unimolecular Reaction Kinetics in the High-Pressure Limit without Collisions.
参考中文标题：单分子反应动力学的高压无碰撞极限。
文献摘要：Molecular activation by blackbody photons, first postulated in 1919 by Perrin, plays a dominant role in the unimolecular dissociation of large ions trapped at low pressure in a Fourier-transform mass spectrometer. Under readily achievable experimental conditions, molecular ions of the protein ubiquitin equilibrate with the blackbody radiation field inside the vacuum chamber. The internal energy of a population of these ions is given by a Boltzmann distribution. From the temperature dependence of unimolecular dissociation rate constants measured in the zero-pressure limit, Arrhenius activation parameters equal to those in the high-pressure limit are obtained.
参考中文摘要：分子活化黑体光子，首先假定在1919年由睿，扮演了在一傅立叶低压离子被困大单分子分解主导作用变换质谱仪。在容易实现的实验条件下，与真空室内部的黑体辐射领域的泛素蛋白分子离子达到平衡。在这些离子人口内部能量给予一玻尔兹曼分布。从单分子解离率在零衡量压力的极限，阿伦尼乌斯活化参数相等的高压限制这些常数的温度依赖性得到。
作者单位：Contribution from the Department of Chemistry, University of California, Berkeley, California 94720.
文献来源：Journal of the American Chemical Society. 118(43):10640-4, 1996 Oct.